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多壁碳纳米管修饰电极对儿茶素的电催化作用
引用本文:李 静,李景印,郭玉凤,段惠敏,王未肖.多壁碳纳米管修饰电极对儿茶素的电催化作用[J].河北科技大学学报,2006,27(4):282-284.
作者姓名:李 静  李景印  郭玉凤  段惠敏  王未肖
作者单位:河北科技大学理学院,河北,石家庄,050018
摘    要:用循环伏安法研究了儿茶素在玻碳电极(GCE)和多壁碳纳米管修饰玻碳电极(MWCNT/GCE)上的电化学行为,探讨了电极反应机理。结果表明:MWCNT/GCE对儿茶素具有显著的电催化作用,儿茶素在MWCNT/GCE上的氧化还原峰电位差比在GCE上明显减小,且峰电流显著增加。电极反应为2电子、2质子转移的准可逆反应过程。

关 键 词:儿茶素  多壁碳纳米管修饰电极  循环伏安法  交流阻抗
文章编号:1008-1542(2006)04-0282-03
收稿时间:2006/9/4 0:00:00
修稿时间:2006年9月4日

Electrocatalytic action of catechin at modified electrode of multi-walled carbon nanotube
LI Jing,LI Jing-yin,GUO Yu-feng,DUAN Hui-min and WANG Wei-xiao.Electrocatalytic action of catechin at modified electrode of multi-walled carbon nanotube[J].Journal of Hebei University of Science and Technology,2006,27(4):282-284.
Authors:LI Jing  LI Jing-yin  GUO Yu-feng  DUAN Hui-min and WANG Wei-xiao
Institution:College of Sciences, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China;College of Sciences, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China;College of Sciences, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China;College of Sciences, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China;College of Sciences, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China
Abstract:The electrochemical behaviors of catechin on the GCE and MWCNT/GCE were studied by cyclic votammetry,and the mechanism of electrode reaction was discussed.The results indicate that MWCNT/GCE has obvious electrocatalytic effect on catechin,and the catechin redox peak potential difference is smaller on the MWCNT/GCE than that on the bare GCE,but peak current greatly increases.The electrode reaction of catechin is two-electron and two-proton quasi reversible process.
Keywords:catechin  multi walled carbon nanotube modified electrode  cyclic voltammetry method  impedance
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