Photocatalytic degradation pathways and adsorption modes of H-acid in TiO2 suspensions |
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Authors: | Pan Gang Wang Dan Liu YuanYuan |
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Institution: | State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences,Beijing 100085, China |
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Abstract: | Effect of adsorption mode on photodegradation of H-acid in TiO2 suspension was studied using DFT calculation, UV-Vis spectroscopy, FTIR, and ionic chromatography. At pH 2.5, H-acid was
adsorbed on TiO2 surfaces by one dissociated sulfonic group. The adsorbed sulfonic group was attacked by surface ·OH, resulting in the production
of SO4
2− and the cleavage of the naphthalene ring. At pH 5.0, H-acid was adsorbed on TiO2 surfaces by two sulfonic groups. The two adsorbed sulfonic groups were simultaneously attacked by surface ·OH, leading to
a faster initial production of SO4
2− and initial degradation rate of H-acid than those under pH 2.5. Microscopic adsorption structures may be more important than
adsorption amount in controlling the photodegradation pathways of organic pollutants. |
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Keywords: | H-acid TiO2 photocatalytic degradation adsorption organic pollutants |
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