| 有机电解质活度系数的MSA计算 |
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| 引用本文： | 凌月 宋文煜. 有机电解质活度系数的MSA计算[J]. 南京理工大学学报(自然科学版), 1994, 0(1): 91-96 |
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| 作者姓名： | 凌月 宋文煜 |
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| 作者单位： | 南京理工大学化工学院 |
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| 摘 要： | 该文应用ＭＳＡ模型理论，并考虑溶质－溶剂相互作用的贡献，对一系列浓度的有机电解质（ＭＡｃ，Ｍ＝Ｌｉ，Ｎａ，Ｋ，Ｒｂ，Ｃｓ；ＲＣＯＯＮａ，Ｒ＝Ｈ，ＣＨ＿３，Ｃ＿２Ｈ＿５，Ｃ＿３Ｈ＿７，Ｃ＿４Ｈ＿９，Ｃ＿５Ｈ＿（１１））在水溶液中的活度系数进行了理论计算，计算结果与文献实验值吻合较好。最后还对各相互作用项的贡献及模型的适用性进行了讨论。
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| 关 键 词： | 有机电解质，活度系数，平均球模型近似（MSA） |
The Calculation of Activitv Coefficients for Organic Electrolytes According to Mean Spherical Approximation. |
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| Lin Yue. The Calculation of Activitv Coefficients for Organic Electrolytes According to Mean Spherical Approximation.[J]. Journal of Nanjing University of Science and Technology(Nature Science), 1994, 0(1): 91-96 |
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| Authors: | Lin Yue |
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| Abstract: | Using the mean spherical approximation(MSA),accompanied by the consideration of solute-solvent interactions,this work is a theoretical calculation of activitv coefficient for several organic electrolytes(i.e.MAC,M=Li,Na,K,Rb,Cs;RCOONa,R=H,CH3,C2H5,C3H7,C4H9,C5H11)in 0.0-2.0 mole per kg-solvent range,The results are in good accordance with those from literature.A short discussion about the contributions from each interaction item and the applicability of the theory is given. |
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| Keywords: | organic electrolyte activity coefficient mean spheri-cal approximation |
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