| 大环化合物八甲基环二十碳四烯八酮的合成 |
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| 引用本文： | 殷彩霞,高竹林,黄荣.大环化合物八甲基环二十碳四烯八酮的合成[J].云南大学学报(自然科学版),2003,25(1):48-49,52. |
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| 作者姓名： | 殷彩霞 高竹林 黄荣 |
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| 作者单位： | 1. 云南大学,应用化学系,云南,昆明,650091
2. 云南大学,实验中心,云南,昆明,650091 |
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| 摘 要： | 通过呋喃和丙酮在酸性溶液中的缩合,得到大环化合物八甲基四氧杂口夸哒烯(1),化合物(1)经间氯过氧苯甲酸氧化,得八甲基环二十碳四烯八酮(2).化合物(1)和(2)的结构均经IR,1HNMR,13CNMR,MS得到验证.
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| 关 键 词： | 八甲基环二十碳四烯八酮 大环化合物 八甲基四氧杂口夸哒烯 |
| 文章编号： | 0258-7971(2003)01-0048-02 |
Synthesis of a macrocyclic compound-octamethylcy cloeicosatetraeneoctaketone |
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| YIN Cai-xia,GAO Zhu-lin,HUANG Rong.Synthesis of a macrocyclic compound-octamethylcy cloeicosatetraeneoctaketone[J].Journal of Yunnan University(Natural Sciences),2003,25(1):48-49,52. |
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| Authors: | YIN Cai-xia GAO Zhu-lin HUANG Rong |
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| Institution: | 1. Department of Chemistry, Yunnan University, Kunming 650091, China;2. Experimental Center, Yunnan University, Kunming 650091, China |
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| Abstract: | A macrocyclic compound,octamethylcycloeicosatetraeneoctaketone,was synthesized through two step reactions.Firstly,octamethyltetroxaquaterene (1) was obtained by condensation of furan and acetone.Octamethylcycloeicosatetraeneoctaketone (2) was synthesized by oxidation of compound(1)using m-chloroperoxybenzic acid.Compound(1)and compound(2) were identified by analysis of spectral data of IR,MS, 1HNMR,13CMNR. |
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| Keywords: | octamethylcycloeicosatetraeneoctaketone macrocyclic compounds octamethyltetroxaquaterene |
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