| 2,6-二甲基-N-庚烷基吗啉与瓜环作用的~1HNMR分析 |
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| 引用本文： | 姚幸茹,黄英,薛赛凤,祝黔江,陶朱.2,6-二甲基-N-庚烷基吗啉与瓜环作用的~1HNMR分析[J].贵州大学学报(自然科学版),2012,29(2):13-15,38. |
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| 作者姓名： | 姚幸茹 黄英 薛赛凤 祝黔江 陶朱 |
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| 作者单位： | 贵州省大环化学及超分子化学重点实验室,贵州 贵阳,550025 |
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| 基金项目： | 国家自然科学基金，贵州省教育厅自然科学基金，贵州省科技厅自然科学基金，贵州省优秀科技教育人才省长专项基金，贵州大学人才引进项目 |
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| 摘 要： | 合成制备了2,6-二甲基-N-庚烷基吗啉及其盐酸盐客体分子,利用1H NMR考察了对称四甲基六元瓜环、七元瓜环以及八元瓜环与2,6-二甲基-N-庚烷基吗啉及盐酸盐的相互作用,结果表明上述瓜环均能与2,6-二甲基-N-庚烷基吗啉及其盐酸盐发生相互作用,并选择性包结烷基部分,形成主客体包结配合物。
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| 关 键 词： | 2 6-二甲基-N-庚烷基吗啉 系列瓜环 1HNMR 主客体包结配合物 |
1H NMR of interaction between cucurbit [n] urils and 2,6-Dimethyl-N-heptylmorpholine |
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| YAO Xing-ru
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HUANG Ying
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XUE Sai-feng
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ZHU Qian-jiang
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TAO Zhu.1H NMR of interaction between cucurbit [n] urils and 2,6-Dimethyl-N-heptylmorpholine[J].Journal of Guizhou University(Natural Science),2012,29(2):13-15,38. |
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| Authors: | YAO Xing-ru HUANG Ying XUE Sai-feng ZHU Qian-jiang TAO Zhu |
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| Institution: | (Key Laboratory of Macrocyelic and Supramolecular Chemistry of Guizhou Province,Guizhou University,Guiyang 550025) |
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| Abstract: | 2,6-Dimethyl-N-heptylmorpholine was synthesized,and interaction of this guest with cucurbitn]urils,such as symmetric tetramethylcucurbituril,cucurbit7]uril and cucurbit8]uril was investigated by using 1H NMR technique.The experimental results show that all three cucurbitn]urils can form host-guest inclusion complexes in which the heptyl moiety was preferred to be included in the cavity of the in cucurbitn]urils. |
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| Keywords: | 2 6-Dimethyl-N-heptylmorpholine cucurbit[n]urils 1H NMR host-guest inclusion complexes |
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