首页 | 本学科首页   官方微博 | 高级检索  
     检索      

铽-恩诺沙星稀土药物配合物的合成及发光性
引用本文:王莹,王丽芳,肖月,马冬云,张云杰,袁寰,杜永祥.铽-恩诺沙星稀土药物配合物的合成及发光性[J].吉首大学学报(自然科学版),2019,40(1):69.
作者姓名:王莹  王丽芳  肖月  马冬云  张云杰  袁寰  杜永祥
作者单位:佳木斯大学药学院,黑龙江佳木斯,154007;佳木斯市第二中学,黑龙江佳木斯,154007;辽宁阜新高等专科学校工程系,辽宁阜新,123001
基金项目:国家自然科学基金资助项目(81601616);黑龙江省教育厅科学研究项目(2016-KYYWF-0113);黑龙江省卫生厅科学研究项目(2016-319);黑龙江省大学生创新创业项目(201610222107);佳木斯大学重点科研项目(12Z1201516)
摘    要:采用沉淀法合成了以药物恩诺沙星(ENRO)为第一配体,邻菲罗啉(Phen)为第二配体的稀土铽药物配合物,采用元素分析、紫外光谱、红外光谱法初步表征配合物结构,并对其荧光性质进行了考察.结果显示,配体与稀土铽离子之间发生了配位,生成了新的稀土配合物;配合物荧光光谱中显示出铽离子的4个特征峰,发出绿色荧光,荧光性较好;发射光谱中存在较强配体峰,说明能量传递不完全.

关 键 词:稀土配合物    恩诺沙星

Study on Synthesis,Characterization and Luminescence Property of Terbium-Enrofloxacin Rare Earth Complex
WANG Ying,WANG Lifang,XIAO Yue,MA Dongyun,ZHANG Yunjie,YUAN Huan,DU Yongxiang.Study on Synthesis,Characterization and Luminescence Property of Terbium-Enrofloxacin Rare Earth Complex[J].Journal of Jishou University(Natural Science Edition),2019,40(1):69.
Authors:WANG Ying  WANG Lifang  XIAO Yue  MA Dongyun  ZHANG Yunjie  YUAN Huan  DU Yongxiang
Institution:(1.College of Pharmacy,Jiamusi University,Jiamusi 154007,Helongjiang China;2.Jiamusi Second Middle School,Jiamusi 154007,Helongjiang China;3.Engineering Department,Fuxin Higher Training College,Fuxin 123001,Liaoning China)
Abstract:The rare earth terbium complex with drug ligands of the enrolfloxacin as the first ligand and the phenanthroline as the second ligand was synthesized by precipitation method.The structure of the complex was characterized by elemental analysis,ultraviolet spectroscopy and infrared spectroscopy and the fluorescence properties were explored.The results showed that the terbium ion (III) and the ligand were coordinated together,and a new rare earth complex was formed.The four characteristic peaks of terbium ions appeared in fluorescence spectrum of the complex,and as a result the complex emitted green fluorescence with rather good fluorescence performance.Also there existed rather strong peaks coming from ligands in emission spectrum,indicating that the energy transfer efficiency was not complete in the complex.
Keywords:complexes of rare earth                                                                                                                        terbium                                                                                                                        enrofloxacin                                                                                                                        luminescence property
本文献已被 CNKI 万方数据 等数据库收录!
点击此处可从《吉首大学学报(自然科学版)》浏览原始摘要信息
点击此处可从《吉首大学学报(自然科学版)》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号