| Fluorinated Hyperbranched Poly（urea-urethane）s Containing Reactive Groups： Synthesis, Characterization and Application on Cotton Fabric |
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| 引用本文： | 汤威宜,黄焰根,卿凤翎.Fluorinated Hyperbranched Poly（urea-urethane）s Containing Reactive Groups： Synthesis, Characterization and Application on Cotton Fabric[J].东华大学学报(英文版),2011,28(3):233-238. |
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| 作者姓名： | 汤威宜 黄焰根 卿凤翎 |
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| 作者单位： | [1]Key Laboratory of Science ＆ Technology of Eco-Textiles, Ministry of Education, Donghua University, Shanghai 201620, China [2]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| 基金项目： | National Natural Science Foundation of China（No.21072028）; Shanghai Municipal Scientific Committee,China（No.08JC1400400） |
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| 摘 要： |
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Fluorinated Hyperbranched Poly(urea-urethane) s Containing Reactive Groups:Synthesis, Characterization and Application on Cotton Fabric |
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| TANG Wei-yi,HUANG Yan-gen,QING Feng-ling.Fluorinated Hyperbranched Poly(urea-urethane) s Containing Reactive Groups:Synthesis, Characterization and Application on Cotton Fabric[J].Journal of Donghua University,2011,28(3):233-238. |
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| Authors: | TANG Wei-yi HUANG Yan-gen QING Feng-ling |
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| Institution: | 1. Key Laboratory of Science & Technology of Eco-Textiles, Ministry of Education, Donghua University, Shanghai 201620, China
2. Key Laboratory of Science & Technology of Eco-Textiles, Ministry of Education, Donghua University, Shanghai 201620, China ;Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | A series of hyperbranched poly(urea-urethane) s (HPUs)containing short fluoroalkyl chain and reactive groups (HPUFs)capable as hydrophobic and oleophobic coating materials were synthesized.The obtained polymers were characterized by FTIR ( fouier transform-infrared spectroscopy ),1 H NMR ( nuclear magnetic resonance),13C NMR,19F NMR,GPC(gel permeation chromatography),TGA ( thermogravimetric analyzer),and XPS (X-ray photoelectron spectroscopy) analyses.Highly hydrophobic and oleophobic cotton fabrics could be achieved from these fluorinated hyperbranched polymers by solution-immersion coating method.The static contact angles reached to 143°,114°,and 92° for water,hexadecane,and decane,respectively.The water and oil repellency ratings were 90 and 6,respectively,and still kept 80 and 5.respectively,after 10 soaping cycles at 50℃. |
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| Keywords: | hyperbranched poly( urea-urethane ) s fluoropolymer coatings hydrophobic oleophobic |
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