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Mg-Zr处理对FH40级船板钢铸态夹杂物特征的影响
引用本文:李小兵,王德永,刘承军,姜茂发. Mg-Zr处理对FH40级船板钢铸态夹杂物特征的影响[J]. 东北大学学报(自然科学版), 2014, 35(4): 529-533. DOI: 10.3969/j.issn.1005-3026.2014.04.017
作者姓名:李小兵  王德永  刘承军  姜茂发
作者单位:(东北大学 多金属共生矿生态化冶金教育部重点实验室, 辽宁 沈阳110819)
基金项目:国家自然科学基金资助项目(50904017);中央高校基本科研业务费专项资金资助项目(N120602005);中国博士后科学基金资助项目(2011M500823)
摘    要:采用定量金相及SEM-EDS手段对Mg,Zr及Mg-Zr处理FH40级船板铸钢中夹杂物粒径分布、平均粒径、总数量、总面积及成分、形貌等特征进行系统研究.结果表明,Mg,Zr及Mg-Zr处理后铸锭夹杂物平均粒径下降,夹杂物总数量增加.Mg的质量分数为0024%时,夹杂物中MgO平均质量分数为1257%,变质不充分;Mg的质量分数增加至0072%后,夹杂物中MgO平均质量分数为3558%,实现了氧化铝向MgO·Al2O3的充分变质,且夹杂物粒径明显减小.003%Zr处理后,铸锭夹杂物以Al2O3+MnS,Al-Zr-O+MnS为主;低Mg+高Zr,高Mg+低Zr,高Mg+高Zr处理炉次试验钢铸锭中均发现了含Zr夹杂物,其中高Mg+高Zr炉次形成了ZrO2夹杂,该类夹杂物被MgO·Al2O3包裹,团聚现象明显.

关 键 词:船板钢  夹杂物  Mg  Zr  变质  

Effects of Mg Zr Combined Treatment on Characteristics of Inclusions in FH40 Ship Building Steel Ingots
LI Xiao bing,WANG De yong,LIU Cheng jun,JIANG Mao fa. Effects of Mg Zr Combined Treatment on Characteristics of Inclusions in FH40 Ship Building Steel Ingots[J]. Journal of Northeastern University(Natural Science), 2014, 35(4): 529-533. DOI: 10.3969/j.issn.1005-3026.2014.04.017
Authors:LI Xiao bing  WANG De yong  LIU Cheng jun  JIANG Mao fa
Affiliation:Key Laboratory for Ecological Metallurgy of Multimetallic Mineral
Abstract:The characteristics such as particle size distribution, average particle size, total amount and chemical composition of FH40 ship building steels formed by Mg, Zr, Mg Zr combined treatment were investigated by the quantitative metallographic and SEM EDS methods. The results showed that the average particle size decreased while the total amount of inclusions increased after Mg, Zr, Mg Zr treatment. With 0024%Mg addition, the average mass fraction of MgO was 1257% in the inclusions, which was not fully modified; With 0072%Mg addition, the average mass fraction of MgO was 3558%, in the inclusions which meant that Al2O3 completely translated into MgO·Al2O3, and the size of inclusions decreased obviously. With 003% Zr addition, the main inclusions of the ingot were mainly Al2O3+MnS, Al Zr O+MnS. The Zr containing inclusions were all found after Mg Zr combined treatment with the amount of the Mg and Zr additions changed as follow low Mg+high Zr, high Mg+low Zr and high Mg+high Zr. Especially, ZrO2 inclusions wrapped with MgO·Al2O3were found in the high Mg+high Zr treated steel with the apparent tendency to be aggregated.
Keywords:ship building steel   inclusions   magnesium   zirconium   modification
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