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芳酮季铵盐光产碱剂的合成与表征
引用本文:钟荣,杨建文,曾兆华,陈用烈. 芳酮季铵盐光产碱剂的合成与表征[J]. 中山大学学报(自然科学版), 2006, 45(1): 53-57
作者姓名:钟荣  杨建文  曾兆华  陈用烈
作者单位:中山大学化学与化学工程学院,广东,广州,510275
基金项目:国家自然科学基金资助项目(60378029),广东省自然科学基金资助项目(011104)
摘    要:以苯乙酮、对甲氧基苯乙酮、萘乙酮、4-甲基二苯甲酮生色团为母体、杂环叔胺三亚乙基二胺、吡啶、3-甲基吡啶和四苯硼盐为原料,合成了12个四苯硼季铵盐光产碱剂,产物经熔点测量、元素分析、FT-IR、1H NMR表征,考察了其吸收光谱等特性。

关 键 词:芳酮  季铵盐  四苯硼盐  光产碱剂  合成
文章编号:0529-6579(2006)01-0053-05
收稿时间:2005-05-26
修稿时间:2005-05-26

Synthesis of Quaternary Ammonium Salt Photobase Generator with Arone
ZHONG Rong,YANG Jian-wen,ZENG Zhao-hua,CHEN Yong-lie. Synthesis of Quaternary Ammonium Salt Photobase Generator with Arone[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2006, 45(1): 53-57
Authors:ZHONG Rong  YANG Jian-wen  ZENG Zhao-hua  CHEN Yong-lie
Affiliation:School of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou 510275 ,China
Abstract:Twelve quaternary ammonium salt photobase generators with arone were synthesized by three-step method.The conditions of synthesis and spectral properties of these photobase generators were investigated.Their structures were confirmed by FT-IR,~1HNMR and elemental analysis.
Keywords:arone  quaternary ammonium salt  tetraphenyl borate  photobase generator  systhesis
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