| 镍(Ⅱ)含氮配体配合物的热分解研究 |
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| 引用本文： | 余玉叶,祝慧.镍(Ⅱ)含氮配体配合物的热分解研究[J].浙江师范大学学报(自然科学版),2006,29(3):306-310. |
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| 作者姓名： | 余玉叶 祝慧 |
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| 作者单位： | 1. 金华职业技术学院,浙江,金华,321017
2. 浙江师范大学,化学与生命科学学院,浙江,金华,321004 |
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| 摘 要： | 用非等温热重法研究了N i(NH3)6]C l2、N i(py)4]C l2、N i(en)3]C l2、N i(b ipy)2]C l2、N i(phen)2]C l2五种配合物在氮气、氧气气氛下的热分解反应机理,比较得出了2种条件下5种配合物的热稳定性;并对配合物N i(py)4]C l2在不同条件下特定分解阶段的非等温热重分析数据采用ACHAR法和COATS-REDFERN法进行了拟合,得出了相应分解阶段该配合物的热分解机理.
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| 关 键 词： | 热分解动力学机理 热分析 非等温法 镍(Ⅱ)配合物 |
| 文章编号： | 1001-5051（2006）03-0306-05 |
| 收稿时间： | 2006-02-15 |
| 修稿时间： | 2006-03-28 |
Calorimetric study and thermal analysis of nickel( Ⅱ ) complexes with nitrogen-containing ligands |
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| YU Yuye,ZHU Hui.Calorimetric study and thermal analysis of nickel( Ⅱ ) complexes with nitrogen-containing ligands[J].Journal of Zhejiang Normal University Natural Sciences,2006,29(3):306-310. |
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| Authors: | YU Yuye ZHU Hui |
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| Institution: | 1. Jinhua College of Profession and Technology. Jinhua Zhejiang 321017, China; 2. College of Chemistry and lafe Sciences, Zhejiang Normal University, Jinhua Zhejiang 321004. China |
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| Abstract: | The kinetic mechanism of thermal decomposition of \Cl_2,\Cl_2,\Cl_2,\Cl_2 and \Cl_2 were studied by non-isothermally TG method in nitrogen and oxygen atomsphere.The data from non-isothermally experiments were analyzed by ACHAR and COATS-REDFERN method.The kinetic mechanism of thermal decomposition and the heat-stability of \Cl_2 complex in two conditions were studied also. |
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