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稀土硝酸盐与邻香兰素缩邻苯二胺配合物的合成与表征
引用本文:范玉华,毕彩丰,郑庚修,姜润田. 稀土硝酸盐与邻香兰素缩邻苯二胺配合物的合成与表征[J]. 济南大学学报(自然科学版), 1996, 0(3)
作者姓名:范玉华  毕彩丰  郑庚修  姜润田
作者单位:山东建材学院应用化学系
摘    要:
由邻香兰素缩邻苯二胺(以L表示)与稀土硝酸盐合成了2种新固体配合物。并对合成的配合物进行了元素分析和红外光谱、紫外光谱、差热—热重、摩尔电导分析,确定配合物的组成为〔LnL(NO3)2〕NO3(Ln=La,Tb),推断出了配合物可能的结构。

关 键 词:双希夫碱;稀土硝酸盐;配合物

SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF LANTHANOID NITRATES WITH O VANILLIN O PHENYLENEDIAMINE
Fan Yuhua Bi Caifeng Zheng Gengxiu Jiang Runtian. SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF LANTHANOID NITRATES WITH O VANILLIN O PHENYLENEDIAMINE[J]. Journal of Jinan University(Science & Technology), 1996, 0(3)
Authors:Fan Yuhua Bi Caifeng Zheng Gengxiu Jiang Runtian
Abstract:
Two new solid complexes of lanthanoid nitrates with bis schiff base (L) derived from o vanillin and o phenylenediamine have been synthesized and characterized by elemental analysis,DTA TG,IR,uv,molar conductance analysis.The composition of the complexes was confirmed to be LnL(NO 3) 2 NO 3 (Ln=La,Tb).The possible structure and some properties of the complexes were studied.
Keywords:bis schiff base  lanthanoid nitrate  complex
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