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水热法合成Ce-ZnSnO3材料及其对正丁醇的气敏性能
引用本文:薛康,姜丽丽,侯新刚,陈伊星. 水热法合成Ce-ZnSnO3材料及其对正丁醇的气敏性能[J]. 兰州理工大学学报, 2021, 47(6): 26
作者姓名:薛康  姜丽丽  侯新刚  陈伊星
作者单位:兰州理工大学 材料科学与工程学院,甘肃 兰州 730050;兰州理工大学 材料科学与工程学院,甘肃 兰州 730050;兰州理工大学 温州泵阀工程研究院,浙江 温州 325000
基金项目:国家自然科学基金(51764039,52064036),浙江省自然科学基金(LQ19E040006)
摘    要:
基于化工厂对正丁醇气体的实际检测需求,采用水热法合成了一种新型的Ce-ZnSnO3材料,通过XRD、SEM、TEM及XPS对材料的晶体结构、微观形貌以及氧缺陷含量进行了表征,并研究了基于Ce-ZnSnO3材料作为气敏传感器涂层材料的可行性.结果表明:在350 ℃条件下,该材料对体积分数0.01%的正丁醇气体的响应值达2 606.473,响应/恢复时间仅为6 s/26 s,同时具有优异的选择性可成为一种检测正丁醇气体的传感材料.

关 键 词:水热法  ZnSnO3  正丁醇  气敏传感器
收稿时间:2021-03-29

Hydrothermal synthesis of Ce-ZnSnO3 material and its gas sensitivity to n-butanol gas
XUE Kang,JIANG Li-li,HOU Xin-gang,CHEN Yi-xing. Hydrothermal synthesis of Ce-ZnSnO3 material and its gas sensitivity to n-butanol gas[J]. Journal of Lanzhou University of Technology, 2021, 47(6): 26
Authors:XUE Kang  JIANG Li-li  HOU Xin-gang  CHEN Yi-xing
Affiliation:1. College of Material Science and Engineering, Lanzhou Univ. of Tech., Lanzhou 730050, China;
2. Wenzhou Engineering Institute of Pump & Valve,Lanzhou Univ. of Tech., Wenzhou 325000, China
Abstract:
A novel Ce-ZnSnO3material was synthesized by hydrothermal method based on the actual detection demand of n-butanol gas in chemical plants. The crystal structure, microstructure and oxygen defect content of the material were characterized by XRD, SEM, TEM and XPS. The feasibility of Ce-ZnSnO3 as coating material for gas sensor was studied. The results showed that the response of the material to n-butanol gas with concentration of 0.01% at 350 ℃ is 2 606.473, the response/recovery time is only 6 s/26 s, and the material has excellent selectivity,which is promised sensing material for the detection of n-butanol gas.
Keywords:hydrothermal  ZnSnO3  n-butanol  gas sensor  
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