| 从范德华力理论看Grunwald-Winstein方程中的Y因子 |
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| 引用本文： | 王风云,陈民生.从范德华力理论看Grunwald-Winstein方程中的Y因子[J].南京理工大学学报(自然科学版),1988(4). |
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| 作者姓名： | 王风云 陈民生 |
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| 作者单位： | 华东工学院化学工程系
(王风云)，华东工学院化学工程系(陈民生) |
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| 摘 要： | 应用范德华力理论,导出了动力学介质效应公式.以叔丁基氯在水—乙醇、水—甲醇、水—二氧六环和水—丙酮体系中的溶剂解反应为研究对象,分析、讨论了Grunwald-Winstein方程中Y因子的具体内容,理论计算的Y值与文献值具有较好的一致性.
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| 关 键 词： | 范德华力[31JA 32FC] 方程[30A] 因子[30B] |
A Discussion of Y Factor in Grunwald-Winstein Equation According to Van Der Waals Theory |
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| Wang Fengyun,Chen Minsheng.A Discussion of Y Factor in Grunwald-Winstein Equation According to Van Der Waals Theory[J].Journal of Nanjing University of Science and Technology(Nature Science),1988(4). |
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| Authors: | Wang Fengyun Chen Minsheng |
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| Institution: | Wang Fengyun;Chen Minsheng |
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| Abstract: | This paper is a theoretical analysis for theY factor in Grunwald-Winstein equation by the van der waals'theory,taking the solvolysis reaction of t-BuClin the mixturesof EtOH-H_2O, Me OH-H_2O, 1, 4-Dioxane-H_2O and Me_2CO-H_2Oas the example. The factor Y in Grunwald-Winstein equation isdiscussed. It is shown that the theoretically calculated velueof Y is more consistent with that in literature. |
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| Keywords: | Van Der waals' Forces Equations Factor |
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