| 一种具有平面型的四齿希夫碱镍(Ⅱ)配合物的合成及其晶体结构 |
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| 引用本文： | 刘巧茹,彭玉洁,刘娟娟,薛灵伟,赵干卿.一种具有平面型的四齿希夫碱镍(Ⅱ)配合物的合成及其晶体结构[J].河南师范大学学报(自然科学版),2014(4):74-76. |
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| 作者姓名： | 刘巧茹 彭玉洁 刘娟娟 薛灵伟 赵干卿 |
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| 作者单位： | 平顶山学院化学化工学院;平顶山学院应用化学重点实验室; |
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| 基金项目： | 河南省教育厅科学技术研究重点项目(14B150058) |
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| 摘 要： | 由水杨醛和2,3-二氨基顺丁烯二腈合成了一种希夫碱,并进一步合成了一种平面型的镍配合物,通过X-射线单晶衍射法对配合物的晶体结构进行了表征.结果表明,该配合物属于正交晶系,空间群Pbcn,晶胞参数a=1.702nm,b=0.6997nm,c=2.591nm,α=90.00(°),β=90.00(°),γ=90.00(°),V=3.085nm3.
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| 关 键 词： | 2 3-二氨基顺丁烯二腈 希夫碱 镍配合物 晶体结构 |
Synthesis and Crystal Structure of a Planar Nickel Complex with a Rigid Quadridentate Schiff Base |
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| LIU Qiaoru;PENG Yujie;LIU Juanjuan;XUE Lingwei;ZHAO Ganqing.Synthesis and Crystal Structure of a Planar Nickel Complex with a Rigid Quadridentate Schiff Base[J].Journal of Henan Normal University(Natural Science),2014(4):74-76. |
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| Authors: | LIU Qiaoru;PENG Yujie;LIU Juanjuan;XUE Lingwei;ZHAO Ganqing |
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| Institution: | LIU Qiaoru;PENG Yujie;LIU Juanjuan;XUE Lingwei;ZHAO Ganqing;School of Chemistry and Chemical Engineering,Pingdingshan University;Key laboratory of applied chemistry,Pingdingshan University; |
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| Abstract: | A plannar nickel complex was synthesized by reacting nickel ion with Schiff base derived from 2,3-diamino-(Z)-2-butenedinitrile and salicylaldehyde.The Crystal structure was determined by X-ray single-crystal diffraction.The crystal of the title compound belongs to the Orthorhombic system,space group Pbcn,a=1.702nm,b=0.6997nm,c=2.591nm,α=90.00(°),β=90.00(°),γ=90.00(°),V=3.085nm3. |
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| Keywords: | 2 3-diamino-(Z)-2-butenedinitrile Schiff's base nickel complexes crystal structure |
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