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冰晶石熔体的电导性质
引用本文:郭慧鹏,叶亚平,李丽芬,周国治. 冰晶石熔体的电导性质[J]. 北京科技大学学报, 2008, 30(9)
作者姓名:郭慧鹏  叶亚平  李丽芬  周国治
作者单位:1. 北京科技大学应用科学学院,北京,100083
2. 北京科技大学冶金与生态工程学院,北京,100083
摘    要:采用电化学交流阻抗谱法研究了Na3AlF6(冰晶石)-Al2O3熔盐体系的总电导以及CaO加入对其电性能的影响. 根据测得的阻抗谱,提出了等效电路,用EvolCRT电化学软件对阻抗数据进行了拟合. 获得了Na3AlF6-Al2O3体系电导率随温度及Al2O3浓度变化的数学关系. CaO加入使得体系电导率增加.

关 键 词:冰晶石熔体  交流阻抗谱  电导率  氧化钙

Electrical conductivity of cryolite melts
GUO Huipeng,YE Yaping,LI Lifen,CHOU Kuochih. Electrical conductivity of cryolite melts[J]. Journal of University of Science and Technology Beijing, 2008, 30(9)
Authors:GUO Huipeng  YE Yaping  LI Lifen  CHOU Kuochih
Abstract:The total electric conductivity of Na3AlF6-Al2O3 slag and the effect of added CaO on the electric conductivity of the slag were investigated by the Ac impedance method of electrochemistry.Equivalent circuits were proposed according to the measured impedance spectra.EvolCRT electrochemical software was used to simulate the impedance data.The correlations of conductivity to slag composition and temperature were studied.The addition of CaO increases the electric conductivity of the system.
Keywords:cryolite melts  AC impedance  conductivity  calcium oxide
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