| Radical Reactions and Its Synthetic Application |
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| 作者姓名： | Takeaki Naito |
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| 作者单位： | Medicinal Chemistry Laboratory, Kobe Pharmaceutical University, Kobe 658-8558, Japan |
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| 摘 要： | 1 Introduction Strategies involving radical reactions have become preeminent tools in organic synthesis. Free radical-mediated cyclization has developed as a powerful method for preparing various types of cyclic compounds via carbon-carbon bond-forming processes. In order to develop effective and convenient methods for the synthesis of biologically active cyclic amines, we have focused our efforts on radical reactions using aldehydes, ketones, and C-C multiple bonds as a radical precursor and…
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| 关 键 词： | 自由基反应 有机物合成 环化过程 循环化合物 |
| 文章编号： | 0427-7104（2005）05-0758-02 |
| 收稿时间： | 2005-08-05 |
| 修稿时间： | 2005-08-05 |
Radical Reactions and Its Synthetic Application |
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| Takeaki Naito.Radical Reactions and Its Synthetic Application[J].Journal of Fudan University(Natural Science),2005,44(5):758-759. |
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| Authors: | Takeaki Naito |
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| Abstract: | Strategies involving radical reactions have become preeminent tools in organic synthesis. Free radical-mediated cyclization has developed as a powerful method for preparing various types of cyclic compounds via carbon-carbon bond-forming processes. In order to develop effective and convenient methods for the synthesis of biologically active cyclic amines, we have focused our efforts on radical reactions using aldehydes, ketones, and C-C multiple bonds as a radical precursor and/or an oxime ether, hydrazone, and nitrone as a radical acceptor. In this lecture, I would like to talk on radical addition-cyclization of oxime ether and its application to the synthesis of martinellines. |
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| Keywords: | radical addition oxime ether martinelline martinellic acid |
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