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The synthesis of a fluorescent chemosensor containing two thiourea groups and its recognition behavior for dicarboxylate anions
Authors:Wang?Fa-jun,Liu?Shun-ying,Hu?Ling,Liu?Xin,He?Yong-bing  mailto:ybhe@whu.edu.cn"   title="  ybhe@whu.edu.cn"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author
Affiliation:(1) College of Chemistry and Molecular Sciences, Wuhan University, 430072 Wuhan, Hubei, China
Abstract:
A novel anion receptor2 bearing anthracene flurophore and thiourea was synthesized and identified by1H NMR, MS, IR and elemental analysis. The interaction between receptor2 and various α, ω-dicarboxylate anions was studied by fluorescence spectrum. The obtained fluorescence data indicate that 1∶1 stoichiometry complex is formed between receptor2 with diferent dicarboxylate anions through a hydrogen-bonging interaction. The selectivity of2 for recognition of different dicarboxylates deponds on chain length of the anionic species. Foundation item: Supported by the National Science Foundation of china (20372054) Biography: WANG Fa-jun (1976-), male, Master Candidate, research direction: supramolecular chemistry.
Keywords:anion receptor  fluorescence  synthesis  anion recognition  
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