| 异丁烯羰基合成Validol反应机理与动力学 |
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| 引用本文： | 王承学,孙敬茹,等.异丁烯羰基合成Validol反应机理与动力学[J].吉林工学院学报,2001,22(3):13-16. |
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| 作者姓名： | 王承学 孙敬茹 |
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| 作者单位： | 吉林工学院化学工程系!吉林长春130012 |
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| 基金项目： | 吉林省科委科学基金资助项目 (吉科合字第 19980 5 6 4) |
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| 摘 要： | 对异丁烯、CO和薄荷醇催化羰基合成Validol的本征反应动力学条件（催化剂、异丁烯和薄荷醇浓度，CO分压）进行了研究，确立了反应机理和动力学方程，给出了反应历程和催化剂环圈。
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| 关 键 词： | Validol 羰基合成 Pd 钯催化剂 动力学 反应机理 异丁烯 |
| 文章编号： | 1006-2939(2001)03-0013-04 |
| 修稿时间： | 2001年7月5日 |
The Kinetics and Mechanism of the Reaction of Synthesizing Validol by Carbonylation of Isobutene |
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| WANG Cheng xue,SUN Jing ru,NING Zhi gang,LIU Gui ying.The Kinetics and Mechanism of the Reaction of Synthesizing Validol by Carbonylation of Isobutene[J].Journal of Jilin Institute of Technology,2001,22(3):13-16. |
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| Authors: | WANG Cheng xue SUN Jing ru NING Zhi gang LIU Gui ying |
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| Abstract: | The kinetic conditions of the intrinsic reaction occurred in the synthesizing Validol by catalyzed carbonylation of isobutene,menthol and CO(type of catalyst used, concentrations of isobutene and menthol, partial pressure of CO)have been studied. The mechanism of the reaction and the kinetic equation are established. The reaction course and the catalytic circulation are given and the kinetic parameters calculated. |
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| Keywords: | validol carbonylation Pd catalyst kinetics mechanism of reaction |
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