气相电子转移过程中第三周期双原子氢化物结构重组能的实验标度

基于重组现象的自交换模型及双原子分子的两类精确势函数（即修正振子势及Ｍｏｒｓｅ势），本文提出了几种在气相电子转移过程中双原子氢化物ＨＡ（Ａ＝Ａｌ，Ｓｉ，Ｐ，Ｓ，Ｃｌ）结构重组能的新的实验标度方法，给出了重组指标——反应物分子的活化半径，并对其所含参数利用实验光谱数据进行了确定。结果表明几种方法都有效地改进了Ｇｅｏｒｇｅ－Ｇｒｉｆｆｉｔｈ经典模型。

THE EXPERIMENTAL SCALE OF STRUCTURAL REORGANIZATION ENERGY FOR DIATOMIC HYDRIDES OF SECOND ROW IN GASEOUS ELECTRON TRANSFER PROCESS

On the basis of self-exchange model of self-exchange model of reorganization phenomena and two di-atomic molecular accurate potential functions(viz.,the modified harmonic oscillator potentialand Morse function),several new scale methods of the structural reorganization energy fordiatomic hydrides(A=Al,Si,P,S,Cl)in gaseous electron transfer process were presented,the reorganization radius the activated radius were given,the parameters involved were deter-mined in terms of experimental spectroscopic data,Results shows that several methods effec-tively improved classical George-Griffith models.