| 在化学修饰[NiFe(CN)_6]~(2-/1~-)电极上D_+-葡萄糖氧化过程的研究 |
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| 引用本文： | 朱则善,成榕榕,赵崇涛,林整榕,郭立平.在化学修饰[NiFe(CN)_6]~(2-/1~-)电极上D_+-葡萄糖氧化过程的研究[J].福建师范大学学报(自然科学版),1992(4). |
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| 作者姓名： | 朱则善 成榕榕 赵崇涛 林整榕 郭立平 |
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| 作者单位： | 福建师大化学系，福建师大化学系，福建师大化学系，福建师大化学系，福州武警指挥学校 |
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| 摘 要： | 测定了化学修饰NiFe(CN)_6]~(2-/1-)电极在NaBr或KBr(以NaNO_3或KNO_3为支持电解质)溶液中的循环伏安图,发现该电极对Br~-的电化学氧化有明显的电催化作用,并对其催化机理进行了讨论。研究结果表明,在D+—葡萄糖电化学氧化制备D_+—葡萄糖酸盐方面,NiFe(CN)_6]~(2-/1-)电极是一种优越的电极材料,在反应过程中NaBr起催化剂的作用。
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| 关 键 词： | 循环伏安图 [NiFe(CN)_6]~(2-/1-) D_+—葡萄糖 葡萄糖酸盐 |
Study of Oxidating Process of D+-Glucose on Nickel Ferrocyanide Film Electrode |
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| Zhu Zeshan Cheng Rongrong Zhao Chongtao Lin Zhenrong.Study of Oxidating Process of D+-Glucose on Nickel Ferrocyanide Film Electrode[J].Journal of Fujian Teachers University(Natural Science),1992(4). |
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| Authors: | Zhu Zeshan Cheng Rongrong Zhao Chongtao Lin Zhenrong |
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| Abstract: | in this paper authors reported that the cyclic voltammograms of the nickel ferrocyanide film electrode in NaBr or KBr solution (the supporting electrolyte is NaNO_3 or KNO_3). It had been found that the nickel ferrocyanide film had obviously part in electrochemical catalyzed oxidation of Br-. The catalyzed mechanism was discussed. The NaBr played a role in action of catalyst in D_+-glucose electrooxidatingto product glyconate. The experiment result showed that nickel ferrocyanide film electrode is a favourable electrode on producting glyconate from D_+-glucose by method of the electrochemical oxidation. |
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| Keywords: | the cyclic voltammograms the nickel ferrocyanide film electrode D_+-glucose glyconate |
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