| 3d过渡金属离子在晶体中的光学和磁学性质理论研究的基础和现状 |
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| 引用本文： | 周一阳,高玲玲. 3d过渡金属离子在晶体中的光学和磁学性质理论研究的基础和现状[J]. 四川师范大学学报(自然科学版), 2011, 34(4): 569-582. DOI: 10.3969/j.issn.1001-8395.2011.04.026 |
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| 作者姓名： | 周一阳 高玲玲 |
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| 作者单位： | 四川师范大学固体物理研究所,四川成都,610066 |
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| 基金项目： | 国家自然科学基金(51074155)资助项目 |
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| 摘 要： | 3d过渡金属离子研究较多的是V2+、Cr2+、Cr3+、Mn2、Mn3+、Fe2+、Fe3+、Co2+、Ni2和Cu2,它们是一类活跃的金属离子,包含这些离子的晶体的光学和磁学性质大多决定于这些离子,这些离子掺杂在其它晶体中常会很大地改变原晶体的物理和化学性质,因而一直是实验和理论研究的热点.介绍了3d过渡金属离子在晶...
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| 关 键 词： | 3d过渡金属离子 晶体场理论 配位场理论 分子轨道理论 光谱 电子顺磁共振谱 磁化强度 磁化率 |
The Optical and Magnetic Properties of 3d Transition-metal Ions in Crystals:A Review of Theoretical Bases and Current Study Situations |
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| ZHOU Yi-yang,GAO Ling-ling. The Optical and Magnetic Properties of 3d Transition-metal Ions in Crystals:A Review of Theoretical Bases and Current Study Situations[J]. Journal of Sichuan Normal University(Natural Science), 2011, 34(4): 569-582. DOI: 10.3969/j.issn.1001-8395.2011.04.026 |
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| Authors: | ZHOU Yi-yang GAO Ling-ling |
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| Affiliation: | ZHOU Yi-yang,GAO Ling-ling(Institute of Solid State Physics,Sichuan Normal University,Chengdu 610066,Sichuan) |
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| Abstract: | A great interest has been devoted to 3d transition metal ions,such as V2+,Cr2+,Cr3+,Mn2+,Mn3+,Fe2+,Fe3+,Co2+,Ni2+ and Cu2+,the optical and magnetic properties of the crystals which contain these metal ions almost depend on the ions.These ions which are doped into other crystals always greatly change the physical and chemical properties of the original crystals,so they are hot studied experimentally and theoretically.This review introduces the crystal-field and molecular-orbital approximation approaches,the ... |
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| Keywords: | 3d transition metal ions crystal-field theory ligand-field theory molecular-orbital theory optical spectra EPR spectra magnetization susceptibility |
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