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Y2O3掺杂对钛酸锶钡基陶瓷结构及介电性能的影响
引用本文:肖宇,周恒为,丁捷,徐凡华,衡晓,雷婷,尹红梅.Y2O3掺杂对钛酸锶钡基陶瓷结构及介电性能的影响[J].伊犁师范学院学报(自然科学版),2014(1):30-33.
作者姓名:肖宇  周恒为  丁捷  徐凡华  衡晓  雷婷  尹红梅
作者单位:[1]伊犁师范学院 物理科学与技术学院,新疆凝聚态相变与微结构实验室,新疆 伊宁 835000 [2]南京大学 物理学院,国家固体微结构重点实验室,江苏 南京 210093
基金项目:新疆自治区科技厅自然基金青年项目(2009211816);新疆自治区科技厅自然基金项目(200821184);新疆普通高校重点学科开放课题(2012ZDXK30).
摘    要:采用固相反应方法制备出(1-x)Ba 0.2Sr0.8Ti0.98Zn0.04O3+xY2O3(x=0,0.02,0.025,0.03)陶瓷材料,并研究Y2O3掺杂对BST-Zn陶瓷样品结构和介电性能的影响,得到以下结论:(1)一定量的Y2O3掺杂,可使BST-Zn陶瓷的晶胞体积增大,晶粒尺寸减小;(2)频率为10Hz时,当掺入2%Y 2 O 3时,ε'最大值可达到885,此时介电损耗为0.024;(3)Y 2 O 3掺入使得低温的弥散相变转化向极化玻璃化转变,并在250K和350K附近出现新的弛豫过程.

关 键 词:钛酸锶钡  介电常数  介电损耗  玻璃化转变

Effect of Y 2 O 3 Doping on the Structure and Dielectric Properties of (Ba 1-x Sr x)TiO 3-based Ceramics
XIAO Yu,ZHOU Heng-wei,DING Jie,XU Fan-hua,HENG Xiao,LEI Ting,YIN Hong-mei.Effect of Y 2 O 3 Doping on the Structure and Dielectric Properties of (Ba 1-x Sr x)TiO 3-based Ceramics[J].Journal of Ili Normal University,2014(1):30-33.
Authors:XIAO Yu  ZHOU Heng-wei  DING Jie  XU Fan-hua  HENG Xiao  LEI Ting  YIN Hong-mei
Institution:( l.Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matter Physics, College of Physical Science and Technology, Yili Normal University, Yining, Xinjiang 835000, China; 2.Department of Physics and National Lab of Solid State Microstructures, Nanjing University, Nanjing, Jiangsu 210093, China)
Abstract:In this paper, (1-x)Ba 0.2 Sr 0.8 Ti 0.98 Zn 0.04 O 3+xY 2 O 3(x=0,0.02,0.025,0.03)ceramic samples which based on 4at% ZnO-doped Ba0.2Sr0.8TiO3 (BST-Zn) ceramics were prepared by the conventional solid-state reaction technique. The effect of Y2O3-doped on microstructures and dielectric properties of the BST-Zn simples were studied systematically. The results show that: (1) With doping suitable amount of Y2O3 maximum contents, the simples’ cell volume increases and grain size decreases;(2) It is found that the dielectric constant is 885 and the dielectric loss is 0.024, when doped 2% Y2O3 in BST-Zn ceramic at 10Hz frequency; (3) with the the Y2O3 doping, BST-Zn’s dispersion phase transition turn into the polarization glass transition phase transition in low temperature area, and two relaxation processes have been found at the area of 250K and 350K.
Keywords:BST  permittivity  dielectric loss  glass transition
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