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Abnormal thermal shock behavior in electrical conductivity of Ti2SnC
Authors:Linquan Zhang  Shibo Li  Xiaodong Chen and Yang Zhou
Institution:Center of Materials Science and Engineering, School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China,Center of Materials Science and Engineering, School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China,Center of Materials Science and Engineering, School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China and Center of Materials Science and Engineering, School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China
Abstract:Some ternary carbide and nitride ceramics have been demonstrated to exhibit abnormal thermal shock behavior in mechanical properties. However, the influence of thermal shock on other properties is not clear. This work reports on the influence of thermal shock on electrical conductivity of Ti2SnC as a representative member of ternary carbides. Abnormal change in electrical conductivity was first demonstrated during quenching Ti2SnC in water at 500–800 °C. The residual electrical conductivity of the quenched Ti2SnC gradually decreased with increasing temperature, but abnormally increased after quenching at 600 °C. The microstructure of surface cracks was characterized. The main mechanism for the abnormal electrical conductivity recovery is that some narrow branching cracks are filled by metallic Sn precipitating from Ti2SnC.
Keywords:Ti2SnC Abnormal thermal shock behavior Recovery Mechanism Crack healing
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