天然纤维素纤维改性及其对水中砷的吸附 |
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引用本文: | 田 野,吴 敏,孟令蝶,黄 勇. 天然纤维素纤维改性及其对水中砷的吸附[J]. 科技导报(北京), 2010, 28(22): 29-32 |
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作者姓名: | 田 野 吴 敏 孟令蝶 黄 勇 |
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作者单位: | 1. 中国科学院化学研究所,北京 1001902. 中国科学院理化技术研究所,北京 100190 |
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摘 要: | 以天然纤维素纤维作为基体材料,通过Ce4+引发的自由基聚合,在其表面接枝聚甲基丙烯酸二甲胺基乙酯,合成了阴离子吸附剂cellulose-g-PDMAEMA(纤维素接枝聚甲基丙烯酸二甲胺基乙酯),用于水中砷的去除。采用场发射扫描电镜(FE-SEM)、傅里叶变换红外光谱(FT-IR)及元素分析对材料进行表征。并且分别用静态吸附实验和动态吸附实验研究材料的吸附性能,结果表明,该阴离子吸附剂可以有效地吸附水中三价砷和五价砷。
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关 键 词: | 纤维素纤维 砷 吸附 水处理 |
收稿时间: | 2010-11-05 |
Modification of Natural Cellulose Fibers for Arsenic Adsorption from Water |
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Abstract: | In this study, the natural cellulose fibers are chosen as template and the anion adsorbent cellulose-g-PDMAEMA is synthesized for arsenic removal. The cellulose fibers were surface modified by graft-polymerization of(N,N-dimethyl aminoethyl methacrylate) (DMAEMA) initiated by Ce4+. The adsorbent was characterized by Field Emission Scanning Electron Microscopy (FE-SEM), Fourier Transform Infrared Spectroscopy(FT-IR) and elemental analyzer. And the adsorption behavior was evaluated by both batch and column experiments. The results indicate that the adsorbent has a high efficiency in the removal of arsenite and arsenate from aqueous solutions. |
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Keywords: | cellulose fibers arsenic adsorption water treatment |
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