| 卟啉阳离子的合成研究 |
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| 引用本文： | 常晓屿,刘云,张军,孙玉娥.卟啉阳离子的合成研究[J].北京工商大学学报(自然科学版),2002,20(1):7-11. |
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| 作者姓名： | 常晓屿 刘云 张军 孙玉娥 |
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| 作者单位： | 北京工商大学,化工学院,北京,100037 |
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| 摘 要： | 报道了从吡咯合成四 (对二甲氨基苯基 )卟啉、5 - ( 3-氨基苯基 ) - 1 0 ,1 5 ,2 0 -三苯基卟啉、间 -四对甲氧基苯基卟啉、卟啉季铵盐 (碘化物、对甲苯磺酸盐 )和相应的金属络合物的合成方法 ,通过改良溶剂和催化剂、优化时间和温度等反应条件 ,提高了产率
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| 关 键 词： | 卟啉季铵盐 金属络合物 催化合成 |
| 文章编号： | 1671-1513(2002)01-0007-05 |
RESEARCH FOR SYNTHESIS OF PORPHYRIN CATION |
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| CHANG Xiao yu,LIU Yun,ZHANG Jun,SUN Yu e.RESEARCH FOR SYNTHESIS OF PORPHYRIN CATION[J].Journal of Beijing Technology and Business University:Natural Science Edition,2002,20(1):7-11. |
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| Authors: | CHANG Xiao yu LIU Yun ZHANG Jun SUN Yu e |
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| Abstract: | Reported the methods for synthesis of tetra (p dimethylamino phenyl) Porphyrin 5 (3 aminophenyl) 10,15,20 triphenyl Porphyrin meso tetrameth oxyphenyl Porphyrin and their cationic compounds (iodide?sulfonate) and the relative metal derivatives. Advanced the yield of the reaction by improving the solvent and the catalyzer and by optimizing the reaction conditions as time and temperatory. |
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| Keywords: | porphyrin quarternary ammonium salt metal complex catalytic synthesis |
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