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熔盐的内压与正负离子间距
引用本文:沈晓燕,黑恩成.熔盐的内压与正负离子间距[J].华东理工大学学报(自然科学版),1999,25(1):101-103.
作者姓名:沈晓燕  黑恩成
作者单位:华东理工大学化学系
摘    要:液体内压的对应状态模型亦适用于熔融碱金属卤化物,模型中的特性常数b正比于晶体中正、负离子间距,这使该模型能够预测熔融碱金属卤化物的内压,预测结果与实验值基本一致。

关 键 词:熔盐  碱金属卤化物  内压  正负离子间距

Internal Pressure of Molten Salts and Distance Between Positive and Negative Ions
Shen Xiaoyan,Hei Encheng and Liu Guojie.Internal Pressure of Molten Salts and Distance Between Positive and Negative Ions[J].Journal of East China University of Science and Technology,1999,25(1):101-103.
Authors:Shen Xiaoyan  Hei Encheng and Liu Guojie
Institution:Shen Xiaoyan,Hei Encheng and Liu Guojie *
Abstract:It is found that the model of corresponding state for the internal pressure of liquids, proposed by our previous work, is also applicable to the molten alkali metal halides. The parameter of model, the characteristic constant b , is directly proportional to the distance between the positive and negative ions in the crystals, which makes the model able to predict internal pressures of molten alkali metal halides. The agreement between the predictive and experimental values is satisfactory.
Keywords:molten salt  alkali  metal halide  internal pressure  law of corresponding state  distance between positive and negative ions
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