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聚–表二元驱油体系性能对比研究
引用本文:靖波,张健,吕鑫,姜维东,冯国智.聚–表二元驱油体系性能对比研究[J].西南石油大学学报(自然科学版),2013,35(1):155-159.
作者姓名:靖波  张健  吕鑫  姜维东  冯国智
作者单位:1.“海洋石油高效开发”国家重点实验室,北京东城100027; 2. 中海油研究总院,北京东城100027
基金项目:国家科技重大专项(2011ZX05024–004);国家973项目(2010CB735505)
摘    要:基于不同分子结构,探讨了表面活性剂分子与聚合物分子、高价金属离子的相互作用机理,认为与钙离子结合能力排序为:十二烷基硫酸钠> 部分水解聚丙烯酰胺> 十二烷基苯磺酸钠,从而导致聚–表二元复配体系黏度的差异。同时,驱油体系驱油实验的结果表明,驱油效率主要受到体系黏度、油水界面张力的影响,但驱油体系性能相近的情况下,具有更大分子截面积的表面活性剂,在驱替过程中,会表现出较好的界面张力保持能力,得到相对较高的驱油效率。

关 键 词:部分水解聚丙烯酰胺  表面活性剂  二元驱  黏度  界面张力  驱油效率  

Comparative Study For The Properties Of Different Surfactant/Polymer Binary Flooding Systems
Jing bo,Zhang Jian,Lü Xin,Jiang Weidong,Feng Guozhi.Comparative Study For The Properties Of Different Surfactant/Polymer Binary Flooding Systems[J].Journal of Southwest Petroleum University(Seience & Technology Edition),2013,35(1):155-159.
Authors:Jing bo  Zhang Jian  Lü Xin  Jiang Weidong  Feng Guozhi
Institution:1. State Key Lab of Offshore Oil Exploitation,Dongcheng,Beijing 100027,China2. Research Institute,CNOOC,Chaoyang,Beijing 100027,China
Abstract:Based on the different molecular structures,interaction mechanisms of surfactant interaction with polymer andhigh-valent metal ions were discussed. The bonding ability of calcium ions ranks as SDS > HPAM >SDBS,which results inthe different viscosities of surfactant/polymer binary systems. Experiments show that oil displacement efficiency was mainlyinfluenced by their viscosity and interfacial tension. However,for similar property systems,the surfactant with bigger molecularsurface cross-sectional area is more helpful to enhance oil displacement efficiency. To some extent,such surfactant wouldmaintain original interfacial tension while flooding.
Keywords:partially hydrolyzed polyacrylamide  surfactant  binary flooding system  viscosity  interfacial tension  oil displacementefficiency  
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