| 高氯酸镁在有机合成中的应用 |
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| 引用本文： | 杨述韬,张利峰,默丽萍.高氯酸镁在有机合成中的应用[J].河北师范大学学报(自然科学版),2007,31(5):652-657. |
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| 作者姓名： | 杨述韬 张利峰 默丽萍 |
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| 作者单位： | 1. 河北师范大学,化学与材料科学学院,河北,石家庄,050016
2. 河北化工医药职业技术学院,化学与环境工程系,河北,石家庄,050031 |
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| 基金项目： | 河北师范大学校科研和教改项目 |
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| 摘 要： | 从有机合成化学的角度,按反应类型综述了高氯酸镁作为Lewis酸催化剂在有机化学中的应用.结果表明高氯酸镁在多种有机反应中表现出非常好的催化性能,其催化反应主要涉及保护基团的形成和裂解、氧化和还原反应、成环反应、加成反应、取代反应和重排反应等.
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| 关 键 词： | 高氯酸镁 Lewis酸 催化 有机合成 应用 |
| 文章编号： | 1000-5854（2007）05-0652-06 |
| 修稿时间： | 2006-06-052006-08-18 |
Organic Reaction Catalyzed by Magnesium Perchlorate |
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| YANG Shu-tao,ZHANG Li-feng,MO Li-ping.Organic Reaction Catalyzed by Magnesium Perchlorate[J].Journal of Hebei Normal University,2007,31(5):652-657. |
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| Authors: | YANG Shu-tao ZHANG Li-feng MO Li-ping |
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| Institution: | 1 .College of Chemistry and Material Sciences,Hebei Normal University,Hebei Shijiazhuang 050016,China; 2.Dapartment of Chemical and Environmental Engineering, Hebei Chemical and Pharmaceutical Vocational Technogy College,Hebei Shijiazhuang 050031,China |
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| Abstract: | From a viewpoint of synthetic organic chemistry, the recent development and application ot magnesium perchlorate as a Lewis acid catalyst in organic reactions are reviewed. Magnesium perchlorate has been demonstrated as a powerful catalyst for many organic reactions. These reactions include the formation and cleavage of common protecting groups,oxidation, reduction, cyclization, addition, substitution and rearrangement. |
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| Keywords: | magnesium perchlorate Lewis acid catalysis organic synthesis application |
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