| 4-(三甲基硅基)苯乙炔单体的合成及其聚合物的制备 |
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| 引用本文： | 祖立武.4-(三甲基硅基)苯乙炔单体的合成及其聚合物的制备[J].齐齐哈尔大学学报(自然科学版),2009,25(4):80-83. |
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| 作者姓名： | 祖立武 |
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| 作者单位： | 齐齐哈尔大学,化学与化学工程学院,黑龙江,齐齐哈尔,161006 |
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| 摘 要： | 通过2种途径合成了4-(三甲基硅基)苯乙炔(SPA)单体,采用核磁共振谱(NMR)和傅里叶变换红外光谱(FT-IR)进行了表征,在Pd(PPh3)2Cl2和金属共催化剂催化下制备了聚4-三甲基硅基苯乙炔poly(SPA).探讨了聚合物的成膜性.
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| 关 键 词： | 含硅基取代聚苯乙炔 聚合物制备 膜 |
4-trimethylsilyl acetylene benzene monomer synthesis and polymer (PSPA) preparation |
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| ZU Li-wu.4-trimethylsilyl acetylene benzene monomer synthesis and polymer (PSPA) preparation[J].Journal of Qiqihar University(Natural Science Edition),2009,25(4):80-83. |
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| Authors: | ZU Li-wu |
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| Institution: | Department of Chemistry and Chemical Engineering;Qiqihar University;Heilongjiang Qiqihar 161006;China |
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| Abstract: | This article 4-trimethylsilylphenyl acetylene(SPA) monomer was synthesized through two schemeand.the monomer were characterized by the NMR and Fourier transform infrared spectroscopy(FT-IR).In Pd(PPh3)2Cl2 and metal catalysts poly SPA were prepared.Its a good film-forming. |
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| Keywords: | containing silicon group substituted phenylacetylene polymer prepare membrane |
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