| Preparation and characterization of poly（styrene／maleic anhydride）／kaolin nanocomposites |
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| 作者姓名： | LIUXuening ZHANGHongtao YANGZhizhong HAChengyong |
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| 作者单位： | GuangzhouInstituteofChemistry,ChineseAcademyofSciences,Guangzhou510650,China |
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| 摘 要： | The direct exfoliation of in situ intercalative copolymerized styrene/maleic anhydride charge-transfer-complex (PSMA) into the inter lamellar spaces of modified kaolin (Kao-DMSO), which was intercalated and surface modified by dimethyl sulfoxide (DMSO), was reported. The nano structure of the composites was investigated by wide-angle X-ray diffraction (XRD) and transmission electron microscopy (TEM). The interaction between kaolin surface and PSMA chain was conformed by FTIR analysis.The XRD results showed that the intercalated polystyrene-maleic anhydride units were arranged in the flattened monolayer arrangements, and the 001 diffraction peak of the original kaolin disappeared. The TEM image showed that thekaolin was exfoliated into nanometer size and dispersed in the polymer matrix. Additionally the thermal stability of the nanocomposites was studied by thermo-gravimetric analysis(TGA), and the resulting thermogram indicated that the thermal stability of the nanocomposites was significantly increased.
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| 关 键 词： | 聚乙烯 高岭土 化学合成物 技术改进 共聚物 |
| 收稿时间： | 2004-08-19 |
Preparation and characterization of poly (styrene/maleic anhydride)/ kaolin nanocomposites |
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| LIUXuening ZHANGHongtao YANGZhizhong HAChengyong.Preparation and characterization of poly (styrene/maleic anhydride)/ kaolin nanocomposites[J].Chinese Science Bulletin,2005,50(13):1320-1325. |
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| Authors: | Email author" target="_blank">Xuening?LiuEmail author Hongtao?Zhang Zhizhong?Yang Chengyong?Ha |
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| Institution: | (1) Guangzhou Institute of Chemistry, Chinese Academy of Sciences, 510650 Guangzhou, China |
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| Abstract: | The direct exfoliation of in situ intercalative copolymerized styrene/maleic anhydride charge-transfercomplex(PSMA)into the inter lamellar spaces of modified kaolin(Kao-DMSo),which WaS intercalated and surfacemodified by dimethyl sulfoxide (DMSO),WaS reported.The nano structure of the composites WaS investieated by wide-angle X-ray diffraction (XRD) and transmission elec-tron microscopy(TEM).The interaction between kaolin surface and PSMA chain WaS conformed by FTIR analysis.The XRD results showed that the intercalated polvsty-rene-malelc anhyvdride units were arranged in the flattened monolayerarrangements.and the 001 diffraction peak of the origlnal kaolin disappeared.The TEM image showed that the kaolin WaS exfoliated into nanometer size and dispersed in the polymer matrix.Additionally the thermal stability of the nanocomposites was studied by thermo-gravimetric analysis (TGA),and the resulting thermogram indicated that the thermal stability of the nanocomposites WaS significantly increased |
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| Keywords: | :exfoliation modified kaolin nanocomposites |
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