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| 镁卟啉催化CO2与环氧化合物偶联合成环碳酸酯的研究 | |
| 引用本文： | 王梅,佘远斌,周贤太,纪红兵.镁卟啉催化CO2与环氧化合物偶联合成环碳酸酯的研究[J].科学技术与工程,2012,12(10):2268-2271. |
| 作者姓名： | 王梅 佘远斌 周贤太 纪红兵 |
| 作者单位： | 1. 北京工业大学环能学院绿色化学与精细化工研究所,北京100124;中山大学化学与化学工程学院,广州510275 2. 北京工业大学环能学院绿色化学与精细化工研究所,北京,100124 3. 中山大学化学与化学工程学院,广州,510275 |
| 基金项目： | 国家自然科学基金重点和面上项目(20776003, 21036009, 21076004和 20976203)；北京市绿色化工学术创新团队计划(PHR201107104)；广东省高等学校高层次人才项目；北京市人才强教深化计划创新团队项目 |
| 摘 要： | 采用类叶绿素化合物四苯基镁卟啉(MgTPP)为催化剂,研究了超临界CO2介质中CO2与系列环氧化物偶联合成环碳酸酯的反应。研究发现MgTPP在超临界CO2介质中表现出很高的催化活性,其TOF(活性转化频率)最高可达18 989 h-1。在优化的反应条件(环氧化物:0.2 mol,三乙胺:5×10-6 mol,MgTPP:1×10-5 mol,P:7.5 MPa,T:140℃t,:1 h)下,主产物环碳酸酯的选择性均超过97%,收率则在74%～94%之间。 |
| 关 键 词： | 镁卟啉 类叶绿素催化剂 超临界CO2 环氧化合物 环碳酸酯 |
| 收稿时间： | 2/2/2012 12:56:41 PM |
| 修稿时间： | 2/2/2012 12:56:41 PM |
The synthesis of the cyclic carbonates by the coupling reaction of CO2 with epoxides catalyzed by MgTPP |
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| Wang Mei,She yuan-bin,ZHOU Xian-tai and JI Hong-bing.The synthesis of the cyclic carbonates by the coupling reaction of CO2 with epoxides catalyzed by MgTPP[J].Science Technology and Engineering,2012,12(10):2268-2271. | |
| Authors: | Wang Mei She yuan-bin ZHOU Xian-tai and JI Hong-bing |
| Institution: | Institute of Green Chemistry and Fine Chemicals, College of Environment and Energy Engineering, Beijing University of Technology,School of Chemistry and Chemical Engineering, Sun Yat-sen University,School of Chemistry and Chemical Engineering, Sun Yat-sen University |
| Abstract: | The synthesis of cyclic carbonates by coupling reactions of supercritical CO2 with epoxides catalyzed by a type of chlorophyll-like catalyst,magnesium porpyrin were investigated.Magnesium meso-tetraphenylporphyrins(MgTPP) were discovered to performe highly catalytic activity in supercritical CO2,and the maximum of TOF(turnover frequency) was 18 989 h(-1).When the reactions were carried out under the optimal condition(epoxide:0.2 mol,triethylamine:5×10(-6) mol,MgTPP:1×10(-5) mol,P:7.5 MPa,T:140 ℃,t:1 h),the selectivity of the main products,cyclic carbonates,was up to 97%,and the yields of cyclic carbonates could reach up to 74%—97%. |
| Keywords: | magnesium porphyrin chlorophyll-like catalyst supercritical CO2 epoxide cyclic carbonate |
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