| MC/PMMA核-壳复合胶粒的制备与表征 |
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| 引用本文： | 莫羡忠,刘永信.MC/PMMA核-壳复合胶粒的制备与表征[J].内蒙古大学学报(自然科学版),2006,37(1):101-104. |
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| 作者姓名： | 莫羡忠 刘永信 |
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| 作者单位： | 1. 北京理工大学国家阻燃材料实验室,北京,100081;广西师范学院化学系,南宁,530001
2. 内蒙古大学自动化系,呼和浩特,010021 |
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| 基金项目： | 广西教育厅科研项目;教育部科学技术研究项目;内蒙古大学校科研和教改项目 |
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| 摘 要： | 采用原位乳液聚合法制备了三聚氰胺氰尿酸盐(M C)/聚甲基丙烯酸甲酯(PMM A)复合胶粒.扫描电镜(SEM)观测、X-光电子能谱(XPS)及热重(TGA)分析结果显示,在M C颗粒表面覆盖了一层PMM A胶膜,形成了具有核-壳结构的M C/PMM A复合胶粒,TGA结果还发现,M C能影响PMM A的热降解过程并促进其成炭.
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| 关 键 词： | MC/PMMA复合胶粒 乳液聚合 制备 表征 |
| 文章编号： | 1000-1638(2006)01-0101-04 |
| 收稿时间： | 2005-02-28 |
| 修稿时间： | 2005-10-12 |
Preparation and Characterization of MC/PMMA Core-shell Composite Latex Particles |
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| MO Xian-zhong,LIU Yong-xin.Preparation and Characterization of MC/PMMA Core-shell Composite Latex Particles[J].Acta Scientiarum Naturalium Universitatis Neimongol,2006,37(1):101-104. |
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| Authors: | MO Xian-zhong LIU Yong-xin |
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| Institution: | 1. National Laboratory of Flame Retardant Materials, Beijing Institute of Technology,Beijing 100081, PRC; 2. Department of Chemistry, Guangxi Teachers Education University, Nanning 530001, PRC ; 3. Department of Automation, NeiMongol University, Hohhot 010021, PRC |
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| Abstract: | Melamine cyanrate(MC)/poly(methyl methacrylate) (PMMA) composite latex particles were prepared via soapless emulsion polymerization.The SEM image,XPS data and TGA analysis reveal that the MC particles were encapsulated by PMMA during polymerization,resulting in the formation of a core-shell structure of MC/PMMA composite latex particles.The TGA data also indicate that MC can affect the thermal degradation and promote charring of PMMA. |
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| Keywords: | MC/PMMA composite particles emulsion polymerization preparation characterization |
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