| 杯(4)芳烃固定相的合成及毛细管柱的研制 |
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| 引用本文： | 王建玲.杯(4)芳烃固定相的合成及毛细管柱的研制[J].河南师范大学学报(自然科学版),1998,26(3):52-54,73. |
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| 作者姓名： | 王建玲 |
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| 作者单位： | 郑州牧业工程高等专科学校 |
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| 摘 要： | 合成了一种新的气相色谱固定相：５，１１，１７，２３－四特丁基－２５，２７－二丁氧基－２６，２８－二（ω－十一碳烯氧基）杯（４）芳烃，其结构经元素分析、红外光谱、核磁共振的数据证实．将这种固定相涂渍在弹性石英毛细管内，测定其柱效、热稳定性、极性及选择性等色谱特性，结果表明：该固定相对某些位置异构体有良好的选择性
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| 关 键 词： | 杯（4）芳烃 毛细管柱 固定相 |
Synthesis and Capillary Column Gas Chromatographic Characterization of Calix(4) Arene Stationary Phase |
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| Abstract: | A new kind of gas chromatography: stationary phases 5,11,17,23-tetra-tert-butyl-25,27-butoxy-26,28-ω-hendecenoxy calix(4) arern was synthesized .Its structure was confirmed by IR, 1HNMR,MS and elemental analysis. The chromatographio characteristics,inclucling column efficiency,thermal stability, polarity and selectivity were studied.The excellent selectivity was obtained in the separations of polar positional isomers. |
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| Keywords: | Calix(4) arene capillary column stationary phase |
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