| 手性硫脲催化剂不对称催化反应及氢键活化作用研究 |
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| 引用本文： | 陈盛楷,买昊,赵志伟,赵博文,刘颖,鲜亮.手性硫脲催化剂不对称催化反应及氢键活化作用研究[J].西北民族学院学报,2014(1):17-21. |
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| 作者姓名： | 陈盛楷 买昊 赵志伟 赵博文 刘颖 鲜亮 |
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| 作者单位： | 西北民族大学化工学院,甘肃兰州730124 |
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| 基金项目： | 国家大学生创新创业训练计划项目（201310742005）、中央高校基本科研业务费专项资金项目（ZYZ2012066）、2012年度留学人员科技活动项目（2012-258）. |
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| 摘 要： | 手性硫脲在不对称催化反应中是一类典型的双功能有机小分子催化剂.文章综述了对称催化反应中手性硫脲的氢键活化理论模型研究现状,重点阐述了手性硫脲催化剂对底物的氢键活化作用的影响规律,并对未来的研究方向提出了观点.
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| 关 键 词： | 手性硫脲 不对称催化 氢键活化 |
Chiral Thiourea Derivatives in Asymmetric Catalysis and Its Hydrogen Bond Activation Theory |
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| CHEN Sheng-kai,MAI Hao,ZHAO Zhi-wei,ZHAO Bo-wen,LIU Ying,XIAN Liang.Chiral Thiourea Derivatives in Asymmetric Catalysis and Its Hydrogen Bond Activation Theory[J].Journal of Northwest Minorities University(Natural Science ),2014(1):17-21. |
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| Authors: | CHEN Sheng-kai MAI Hao ZHAO Zhi-wei ZHAO Bo-wen LIU Ying XIAN Liang |
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| Institution: | (Chemical Engineering College of Northwest University for Nationalities, Lanahou 730030, China) |
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| Abstract: | Chiral thiourea derivative is one of typical bifunctional organic small catalyst in asymmetric catalysis. The research of hydrogen activation theory of chiral thiourea derivative for asymmetric catalysis is reviewed, highlighting the structural characters of chiral thiourea and the influence on the hydrogen bonding activation for substrate. The possible research tendency in this field is also discussed. |
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| Keywords: | Chiral thiourea Asymmetric catalysis Hydrogen bond activation theory |
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