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| 顺丁烯二酸酐与二乙醇胺合成的超支化不饱和聚合物的聚合机理 | |
| 引用本文： | 宋伟强,遆永周,邓刚,吴承训,朱诚身.顺丁烯二酸酐与二乙醇胺合成的超支化不饱和聚合物的聚合机理[J].郑州大学学报(理学版),2007,39(1):96-100. |
| 作者姓名： | 宋伟强 遆永周 邓刚 吴承训 朱诚身 |
| 作者单位： | 1. 东华大学材料科学与工程学院,上海,200051;河南省科学院同位素研究所,郑州,450052 2. 河南省科学院同位素研究所,郑州,450052 3. 东华大学材料科学与工程学院,上海,200051 4. 郑州大学材料科学与工程学院,郑州,450001 |
| 摘 要： | 采用“一步法”由二乙醇胺和顺丁烯二酸酐合成超支化不饱和聚合物,用核磁共振技术对聚合物结构进行表征.通过NMR谱图分析,发现聚合物结构中出现次甲基,以此为基础并结合相关文献报道,对聚合机理进行了分析. |
| 关 键 词： | 二乙醇胺 顺丁烯二酸酐 超支化聚合物 聚合机理 |
| 文章编号： | 1671-6841（2007）01-0096-05 |
| 修稿时间： | 2006-01-10 |
Mechanism of Polymerization of Hyperbranched Polymer Synthesized by Diethanoamine and Maleic Anhydride |
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| SONG Wei-qiang,TI Yong-zhou,DENG Gang,WU Cheng-xun,ZHU Cheng-shen.Mechanism of Polymerization of Hyperbranched Polymer Synthesized by Diethanoamine and Maleic Anhydride[J].Journal of Zhengzhou University:Natural Science Edition,2007,39(1):96-100. | |
| Authors: | SONG Wei-qiang TI Yong-zhou DENG Gang WU Cheng-xun ZHU Cheng-shen |
| Institution: | 1. College of Material Science and Engineering, Donghua University, Shanghai 200051, China; 2. Institute of Isotope, Henan Academy of Sciences, Zhengzhou 450052, China ;3. College of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001 ,China |
| Abstract: | A hyperbranched polymer is successfully prepared by "one pot" polymerization of diethanoamine and maleic anhydride,and characterized by NMR.It is found that methane is formed in the polymer structure.The scheme of polymerization is also analyzed. |
| Keywords: | diethanoamine maleic anhydride hyperbranched polymer scheme of polymerization |
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