| 1,8-萘啶氮氧化物与3d元素高氯酸盐配合物研究 |
| |
| 引用本文： | 甘新民,唐宁,谭民裕,殷小天.1,8-萘啶氮氧化物与3d元素高氯酸盐配合物研究[J].西南师范大学学报(自然科学版),1988(4). |
| |
| 作者姓名： | 甘新民 唐宁 谭民裕 殷小天 |
| |
| 作者单位： | 兰州大学
(甘新民，唐宁，谭民裕)，西南师范大学(殷小天) |
| |
| 摘 要： | 在非水介质中合成出1,8-萘啶氮氧化物与6个3d元素(锰,铁,钴,镍,铜,锌)高氯酸盐的固体配合物.对配合物进行了熔点及溶解性测定.通过元素分析、红外光谱、紫外光谱和摩尔电导等测定.研究了配合物的组成和性质.
|
| 关 键 词： | 1 8-萘啶氮氧化物 高氯酸盐 配位 |
STUDIES ON THE COMPLEXES OF 3d METAL PERCHLORATES WITH1,8-NAPHTHYRIDINE-N-OXIDE |
| |
| G XI MIN T G NING TA M Y.STUDIES ON THE COMPLEXES OF 3d METAL PERCHLORATES WITH1,8-NAPHTHYRIDINE-N-OXIDE[J].Journal of Southwest China Normal University(Natural Science),1988(4). |
| |
| Authors: | G XI MIN T G NING TA M Y |
| |
| Institution: | G XI MIN T G NING TA M Y(Lanzhou University)YIN XIA TIAN (Southwest China Teachers University) |
| |
| Abstract: | The solid complexes of 3d metal perchlorates with 1, 8-naphthyridine-N-oxide (napyo) having the composition Fe(napyo)4(ClO4)3, Cu(napyo)2(ClO4)2 and M(napyo)3(ClO4)2(M=Mn, Co, Ni, Zn) have been synthesized.The series of new complexes have been characterized by elemental analyses, infrared spectra, ultraviolet spectra and molar conductance. The results show that the metal ions in these complexes are coordinated to oxygen atoms and nitrogen atoms of the lig-ands and the perchlorate groups are not coordinated to the metal ions. |
| |
| Keywords: | 1 8-naphthyridine-N-oxide perchiorate coordination |
| 本文献已被 CNKI 等数据库收录！ |
|
