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新型铝电解电容器中导电聚吡咯对电极的形成
引用本文:胡明,张景阳,郝嘉林,刘志刚.新型铝电解电容器中导电聚吡咯对电极的形成[J].天津大学学报(自然科学与工程技术版),2000,33(2):231-235.
作者姓名:胡明  张景阳  郝嘉林  刘志刚
作者单位:天津大学电子信息工程学院!天津300072
基金项目:天津市自然科学基金资助项目!98360 371 1
摘    要:研究了在铝电解电容器介质表面形成导电聚吡咯膜作为电容器对电极的方法。导电聚吡咯的沉积分为两个步骤。首先用化学聚合方法在介质膜上形成一薄层导电聚吡咯大此基础上再进行电化学聚合。实验分析了聚合条件对聚吡咯电导率的影响。制备出电导率力10S/cm的聚吡咯膜和以此为对电极的新型固体铝电解电容器。

关 键 词:导电高分子  聚吡咯  铝电解电容器  电极  电导率

FORMING OF CONDUCTIVE POLYPYRROLE AS COUNTERELECTRODE IN NEW ALUMINUM SOLID ELECTROLYTIC CAPACITOR
HU Ming,ZHANG Jing-yang,HAO Jia-lin,LIU Zhi-gang.FORMING OF CONDUCTIVE POLYPYRROLE AS COUNTERELECTRODE IN NEW ALUMINUM SOLID ELECTROLYTIC CAPACITOR[J].Journal of Tianjin University(Science and Technology),2000,33(2):231-235.
Authors:HU Ming  ZHANG Jing-yang  HAO Jia-lin  LIU Zhi-gang
Abstract:The methods for depositing a conductive polypyrrole film on the surface of a dielectric layer of aluminum electrolytic capacitor as a counterelectrode have been investigated.The deposition of polypyrrole was carried out in two steps.First,a thin conducting polypyrrole film is deposited on the dielectric layer by chemical polymerization,and then synthesized by electrochemical polymerization on the first one.The effects of the polymerization conditions on the conductivity of the polypyrrole are analyzed experimentally.The polypyrrole film with an electrical conductivity of 10 S/cm is prepared and a new aluminum solid electrolytic capacitor with the polypyrrole counterelectrode is produced.
Keywords:conducting polymer  polypyrrole  aluminum solid electrolytic capacitor
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