| 二碘化钐和异氰酸苯酯的作用 |
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| 引用本文： | 袁福根,宋瑞峰,沈琪.二碘化钐和异氰酸苯酯的作用[J].苏州科技学院学报(自然科学版),2000(2). |
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| 作者姓名： | 袁福根 宋瑞峰 沈琪 |
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| 作者单位： | 苏州铁道师范学院化学系!苏州215009(袁福根，宋瑞峰)，苏州大学化学化工系!苏州215006(沈琪) |
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| 基金项目： | 江苏省有机合成重点实验室开放基金!(K98114)，铁道部专项基金!(J98Z32 ) |
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| 摘 要： | 研究了二碘化钐和异氰酸苯酯的反应 ,分离获得了二碘化钐被氧化的产物 SmI2 (THF) 5 ]SmI4(THF) 2 ],并经元素分析、红外光谱和X光单晶衍射分析表征。二碘化钐和异硫氰酸苯酯、二硫化碳、二氧化碳反应 ,也均得到同样的钐络合物。
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| 关 键 词： | 二碘化钐 异氰酸苯酯 晶体结构 |
Reaction of Samarium Diiodide with Phenyl Isocyanate |
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| YUAN Fu gen ,SONG Rui feng ,SHEN Qi.Reaction of Samarium Diiodide with Phenyl Isocyanate[J].Journal of University of Science and Technology of Suzhou,2000(2). |
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| Authors: | YUAN Fu gen SONG Rui feng SHEN Qi |
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| Institution: | YUAN Fu gen 1,SONG Rui feng 1,SHEN Qi 2 |
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| Abstract: | The paper describes the reaction of samarium diiodide with phenyl isocyanate. Samarium diiodide was oxidated to be SmI 2(THF) 5]SmI 4(THF) 2], characterized by elemental analysis, infrared spectra and single crystal X-ray diffraction analysis. The same product was also isolated when samarium diiodide reacted with phenyl isothiocyanate, carbon disulfide and carbon dioxide. |
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| Keywords: | samarium diiodide phenyl isocyanate crystal structure |
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