驱油用聚丙烯酰胺溶液的界面扩张流变特征研究

借助界面扩张流变测量方法,研究了聚合物与正十二烷形成的界面膜特征。主要探讨了液膜稳定过程与界面扩张粘弹模量随测量时间变化的关系、聚合物溶液浓度的影响以及不同聚合物、不同界面膜的流变特征。结果表明,界面粘弹模量的变化反映了膜的吸附平衡过程;正十二烷/聚合物体系膜强度以弹性为主,只是随聚合物浓度增加,粘性模量对膜强度的贡献比例有所上升。聚合物溶液与不同物质所形成的界面具有不同的粘弹性特征,与空气、正十二烷、原油所形成界面的界面扩张粘弹模量E的大小次序为E空气>E正十二烷>E原油,即E随着两相密度差的减小而减小。

Dilational rheological properties of polyacrylamide solutions at interfaces

The changes of interfacial viscoelasticity along with measuring time and the effect of partially hydrolyzed polyacrylamide(PHPAM) concentration and type viscoelasticity at the interface between PHPAM and dodecane were investigated by means of dilational method. The results show that response of interfacial adsorption process can be made by interfacial viscoelasticity. Elasticity plays an important role for PHPAM/dodcane system even though contribution of viscosity in viscoelasticity goes up along with the increase of PHPAM concentration. Moreover, different viscoelasticity characteristics at different interfaces for PHPAM solution were also found. Among those three interfaces were experimented, and the order of the numerical value of viscoelasticity from large to small is PHPAM/air interface, PHPAM/dodecane interface and PHPAM/crude oil interface.