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AAO模板外表面自组织纳米孔洞的差异性研究
引用本文:王强,冯煤生,李春红. AAO模板外表面自组织纳米孔洞的差异性研究[J]. 江西师范大学学报(自然科学版), 2008, 32(6)
作者姓名:王强  冯煤生  李春红
作者单位:首都师范大学,初等教育学院,北京,100080;北京理工大学理学院化学系,北京,100081;北京理工大学爆炸科学与技术国家重点实验室,北京,100081;首都师范大学,初等教育学院,北京,100080;北京理工大学理学院化学系,北京,100081;北京理工大学爆炸科学与技术国家重点实验室,北京,100081
基金项目:国家自然科学基金(20671011,20731002);;首都师范大学青年基金(005230901,085605400)资助项目
摘    要:以草酸为电解液,分别用一次阳极氧化法和二次阳极氧化法制备了阳极氧化铝(AAO,anodic aluminum oxide)模板,在较大范围内得到了纳米孔分布均匀、孔洞大小均一、尺寸可控、排列有序的双通模板.采用扫描电镜(SEM)对其形貌进行表征,发现一次阳极氧化法制得的AAO模板的反面孔洞排列较为规则,而正面的孔洞排列规则性明显不如反面;二次阳极氧化法制备得到的模板正、反面孔洞的排列都比较规则.比较了模板正、反面纳米孔洞的差异,并结合阳极氧化过程中电流的变化,探讨了自组织孔洞的形成机理.目前尚未发现关于纳米孔洞差异性及原因分析的文献报道.

关 键 词:氧化铝模板  阳极氧化法  扫描电镜  自组织机制

Study of the Different Serf-Organized Nano-Pores in External Surface of Anodic Aluminum Oxide Template
WANG Qiang,FENG Mei-sheng,LI Chun-hong. Study of the Different Serf-Organized Nano-Pores in External Surface of Anodic Aluminum Oxide Template[J]. Journal of Jiangxi Normal University (Natural Sciences Edition), 2008, 32(6)
Authors:WANG Qiang  FENG Mei-sheng  LI Chun-hong
Affiliation:1.Elementary Educational College;Capital Normal University;Beijing 100080;China;2.Department of Chemistry;School of Science;Beijing Institute of Technology;Beijing 100082;3.State Key Laboratory of Explosion Science and Technology;Beijing 100081;China
Abstract:Anodic aluminum oxide(AAO) templates were prepared by one-and two-step anodization in oxalic acid solution,respectively.The morphology of the AAO templates were characterized by scanning electron microscopy(SEM) and the result showed that the two-side-open templates have ordered,regular and diameter-controlled nano-pores.It can be seen from the SEM images of the AAO templates that the nano-pores in the back side of the AAO template prepared by one-step anodization were more regular than that in the face sid...
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