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| 多壁碳纳米管氨基化修饰 | |
| 引用本文： | 张斌斌,沈剑锋,胡轶喆,吴利平,叶明新.多壁碳纳米管氨基化修饰[J].复旦学报(自然科学版),2008,47(4). |
| 作者姓名： | 张斌斌 沈剑锋 胡轶喆 吴利平 叶明新 |
| 作者单位： | 1. 复旦大学,材料科学系 2. 复旦大学,聚合物分子工程教育部重点实验室,上海,200433 3. 复旦大学,材料科学系;复旦大学,聚合物分子工程教育部重点实验室,上海,200433 |
| 摘 要： | 将多壁碳纳米管高温处理除去无定形碳、然后用混酸（硫酸／硝酸）对碳纳米管进行表面羧基化．将羧基化碳纳米管与二氯亚砜反应得到酰氯化碳纳米管，然后将其分别与4，4＇-二氨基二苯砜（DDS）、1，3-二（3-氨丙基）-1，1，3，3-四甲基二甲硅醚（＆DA）、4＂，4＂＇-六氟异亚丙基-二（4-苯氧基苯胺）（FA）等二胺反应得到不同氨基化碳纳米管，FTIR，Raman，EDX，XRD，SEM，TGA分别对氨基化碳纳米管的结构与性能进行表征．通过对其在不同溶剂中的分散性的测试，氨基化碳纳米管在乙醇中的分散性明显优于未经修饰过的碳纳米管． |
| 关 键 词： | 多壁碳纳米管 羧基化 酰氯化 氨基化 |
Functionalization of Multi-Walled Carbon Nanotubes Using Diamines |
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| ZHANG Bin-bin,SHEN Jian-feng,HU Yi-zhe,WU Li-ping,YE Ming-xin.Functionalization of Multi-Walled Carbon Nanotubes Using Diamines[J].Journal of Fudan University(Natural Science),2008,47(4). | |
| Authors: | ZHANG Bin-bin SHEN Jian-feng HU Yi-zhe WU Li-ping YE Ming-xin |
| Abstract: | Multi-walled carbon nanotubes(MWNTs)were pre-treated at high temperature to eliminate the amorphous carbon.Functionalized MWNTs were then obtained by carboxylation in a 3∶1 mixture of concentrated H2SO4 and HNO3,acylation in the thionyl chloride and amidation with diamines.The structures of functionalized MWNTs were characterized by FT-IR,Raman spectroscopy,energy dispersive X-Ray fluoresence spectrometer,X-rays diffraction spectroscopy,scanning electron microscopy and thermogravimetic analysis.The dispersion of unctionalized MWNTs was also studied. |
| Keywords: | multi-walled carbon nanotubes carboxylation acylation amidation |
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