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蓝光聚芳醚的合成、光物理及电致发光性能
引用本文:卞春雷,江国新,程延祥,谢志元,王利祥. 蓝光聚芳醚的合成、光物理及电致发光性能[J]. 黑龙江大学自然科学学报, 2011, 28(5): 669-675
作者姓名:卞春雷  江国新  程延祥  谢志元  王利祥
作者单位:中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春,130022
基金项目:国家自然科学基金重点项目(50633040);国家自然科学基金创新研究群体资助项目(20921061)
摘    要:
通过缩聚反应合成了一种含有高效浅蓝光荧光团(2,7-二[4’-二苯胺基苯乙烯基]芴)为侧链的电致发光聚芳醚高分子(PDDPAVF),系统研究了其溶解性、热稳定性、电化学性能、光物理性能和电致发光性能等.结果表明,通过将浅蓝光发射的PDDPAVF与深蓝光发射聚芳醚物理共混,可以实现从深蓝光发射聚芳醚到PDDPAVF的高效...

关 键 词:蓝光高分子  聚芳醚  共混体系  能量转移

Synthesis,photophysical and electroluminescent properties of a novel blue poly(aryl ether)
BIAN Chun-lei,JIANG Guo-xin,CHENG Yan-xiang,XIE Zhi-yuan,WANG Li-xiang. Synthesis,photophysical and electroluminescent properties of a novel blue poly(aryl ether)[J]. Journal of Natural Science of Heilongjiang University, 2011, 28(5): 669-675
Authors:BIAN Chun-lei  JIANG Guo-xin  CHENG Yan-xiang  XIE Zhi-yuan  WANG Li-xiang
Affiliation:BIAN Chun-lei,JIANG Guo-xin,CHENG Yan-xiang,XIE Zhi-yuan,WANG Li-xiang (State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)
Abstract:
A novel poly(aryl ether)(PDDPAVF) containing blue unit in the side chains by a facile,metal-free condensation polymerization were synthesized.The polymer's solubility,thermal stability,electrochemical properties,photophysical properties and electroluminescent properties,etc.were studied.By blending PDDPAVF with a deep blue poly(aryl ether),efficient energy transfer from the deep blue poly(aryl ether) to PDDPAVF can be realized,and intermolecular aggregation of PDDPAVF are suppressed effectively.Single-layer...
Keywords:blue polymers  poly(aryl ether)  blend  energy transfer  
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