| 有机-无机杂化超分子复合物:溶液与表面和界面自组装 |
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| 引用本文： | 吴立新,闫毅.有机-无机杂化超分子复合物:溶液与表面和界面自组装[J].黑龙江大学自然科学学报,2011,28(5):660-668. |
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| 作者姓名： | 吴立新 闫毅 |
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| 作者单位： | 吉林大学化学学院超分子结构与材料国家重点实验室,长春,130012 |
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| 基金项目： | 国家重点基础研究发展计划(973)项目(2007CB808003); 国家自然科学基金资助项目(20973082,20921003,21074046); 111计划资助项目(B06009) |
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| 摘 要： | 多金属氧簇作为一类功能性无机多阴离子,可以通过与有机阳离子的静电作用形成超分子复合物,从而用于自组装体系,获得各种各样杂化超分子结构.这种多阴离子表面修饰的方法一方面改善了多金属氧簇的表面性质,另一方面也为构筑各种超分子组装体提供了新颖结构的两亲性构筑基元并展现了独特的自组装性质.主要总结近年来作者在溶液和界面超分子自...
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| 关 键 词： | 多金属氧簇 超分子组装 杂化材料 |
Organic-inorganic supramolecular complexes:self-assembly in solution and at surface and interface |
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| WU Li-xin,YAN Yi.Organic-inorganic supramolecular complexes:self-assembly in solution and at surface and interface[J].Journal of Natural Science of Heilongjiang University,2011,28(5):660-668. |
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| Authors: | WU Li-xin YAN Yi |
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| Institution: | WU Li-xin,YAN Yi (State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,China) |
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| Abstract: | As a typical family of functional inorganic polyanionic clusters,polyoxometalates(POMs) can form supramolecular complexes with organic cations through electrostatic interaction,and thus be applied for self-assembly,obtaining diverse hybrid supramolecular structures.This method has not only improved the surface properties of the POMs,but also provided amazing amphiphilic building blocks for the construction of various self-assembled mesostructures.In this review,the author summarized the recent research prog... |
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| Keywords: | polyoxometalate supramolecular self-assembly hybrid materials |
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