| 二茂铁的电化学合成 |
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| 引用本文： | 于海涛,邬冰,高颖,池玉娟,张业茂.二茂铁的电化学合成[J].哈尔滨师范大学自然科学学报,1997(6). |
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| 作者姓名： | 于海涛 邬冰 高颖 池玉娟 张业茂 |
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| 作者单位： | 哈尔滨师范大学，哈尔滨工程大学，哈尔滨师范大学 |
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| 摘 要： | 在含有Na+、Cl-、环戊二烯和特性催化剂的无水乙醇溶液中，电解合成得到了二茂铁。阴、阳极均为纯铁电极，采用换向控制，氮气保护。体系温度控制在40℃，电解时恒定电流密度8～14mA／cm2或恒定电位－1．10V～－1．40V之间。产率为78．1％。
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| 关 键 词： | 二茂铁 电化学合成 |
ELECTROSYNTHESIS OF FERROCENE |
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| Yu Haitao, Wu Bing, Gao Ying, Chi Yujuan, Zhang Yiemao.ELECTROSYNTHESIS OF FERROCENE[J].Natural Science Journal of Harbin Normal University,1997(6). |
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| Authors: | Yu Haitao Wu Bing Gao Ying Chi Yujuan Zhang Yiemao |
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| Institution: | Yu Haitao; Wu Bing; Gao Ying; Chi Yujuan; Zhang Yiemao(Harbin Normal University) (Harbin Engineering University) (Harbin Normal University) |
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| Abstract: | The electrodeduction of 1, 3-cyclopentadiene and sodium ion on pure iron electrode in ethylalcohol including chlorine ion has been investigated. The electrosynthesis used the control method that can change the direction of cathod and anode,and gained the product under given conditions which proved ferrocene by IR spectrum and UV-VIS spectum. The productivity is 78.1% . |
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| Keywords: | Ferrocene electrosynthsis |
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