| Acerogenin G和1,7-双-(4-羟基苯基)-1,4,6-庚三烯-3-酮的全合成 |
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| 引用本文： | 兰州大学学报.Acerogenin G和1,7-双-(4-羟基苯基)-1,4,6-庚三烯-3-酮的全合成[J].兰州大学学报(自然科学版),1999,35(2):1. |
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| 作者姓名： | 兰州大学学报 |
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| 作者单位： | （达世俊 李瀛 黄初升 李晓红 李裕林）兰州大学 应用有机化学国家重点实验室，有机化学研究所，甘肃 兰州 730000； |
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| 摘 要： | 以对羟基苯甲醛为起始原料，经保护、羟醛缩合、选择性还原、氧化、去保护等八步反应，完成了两个天然二芳基庚烷类化合物——acerogenin
G和1，7-双-(4-羟基苯基)-1，4，6-庚三烯-3-酮的全合成．
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| 关 键 词： | 二芳基庚烷类化合物 acerogenin G，1，7-双-(4-羟基苯基)-1，4，6-庚三烯-3-酮 全合成 |
| 修稿时间： | 1998-06-29 |
The Total Synthesis of
Acerogenin G and 1,7-Bis-(4-
hydroxyphenyl)-1,4,6-heptatrien-3-one |
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| Da Shijun ,Li Ying ,Huang Chusheng ,Li Xiaohong ,Li Yulin ,Xing Yacheng ,Cen Wen.The Total Synthesis of
Acerogenin G and 1,7-Bis-(4-
hydroxyphenyl)-1,4,6-heptatrien-3-one[J].Journal of Lanzhou University(Natural Science),1999,35(2):1. |
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| Authors: | Da Shijun Li Ying Huang Chusheng Li Xiaohong Li Yulin Xing Yacheng Cen Wen |
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| Institution: | Da Shijun 1,Li Ying 1,Huang Chusheng 1,Li Xiaohong 1,Li Yulin 1,Xing Yacheng 2,Cen Wen 2 |
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| Abstract: | The total syntheses of two new natural diarylheptanoids, Acerogenin G (1) and 1,7 bis (4 hydroxyphenyl) 1,4,6 heptatrien 3 one (2), were accomplished by starting from 4 hydroxybenzaldehyde (3) in eight steps by MOM protection, aldol condensation, selective reduction, oxidation and deprotection. |
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| Keywords: | diarylheptanoids acerogenin G 1 7 bis (4 hydroxyphenyl) 1 4 6 heptatrien 3 one total synthesis |
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