| 金属胶束催化VII：双核配合物金属胶束催化PNPP水解反应动力学 |
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| 引用本文： | 胡伟,冯发美,黄生田,谢家庆,胡常伟,曾宪诚.金属胶束催化VII：双核配合物金属胶束催化PNPP水解反应动力学[J].四川大学学报(自然科学版),2004,41(1):131-136. |
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| 作者姓名： | 胡伟 冯发美 黄生田 谢家庆 胡常伟 曾宪诚 |
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| 作者单位： | [1]四川大学化学学院，成都610064 [2]自贡师范高等科学校，四川自贡653000 |
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| 基金项目： | 国家自然科学基金资助项目(19873031,20173038)，自贡师范高等专科学校校级课题资助 |
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| 摘 要： | 研究了由双核铜配合物和表面活性剂组成的金属胶束催化PNPP水解的动力学和机理。提出了含两个水分子的双核铜配合物催化PNPP水解的动力学数学模型。结果表明：金属胶束催化PNPP水解是分子内反应；两个铜离子在催化PNPP水解过程中具有协同效应；由草酰胺桥联双核铜配合物与表面活性剂组成的金属胶束在催化PNPP水解中表现出高的活性。
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| 关 键 词： | PNPP水解 双核金属胶束 催化 动力学 |
Metallomicellar Catalysis VII:The Kinetics of PNPP Hydrolysis Catalyzed by the Metallomicelle Made of Dinuclear Complex |
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| HU Wei.Metallomicellar Catalysis VII:The Kinetics of PNPP Hydrolysis Catalyzed by the Metallomicelle Made of Dinuclear Complex[J].Journal of Sichuan University (Natural Science Edition),2004,41(1):131-136. |
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| Authors: | HU Wei |
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| Abstract: | The kinetics and the mechanism on PNPP hydrolysis catalyzed by the metallomicelles made up of the complex and the surfactant are investigated. A kinetic mathematical model of PNPP cleavage catalyzed by dinuclear copper(II) complex was proposed. The results showed: the PNPP catalytic hydrolysis was intramolecular reaction in the metallomicelles; the two copper(II) ions revealed the synergistic effects in the PNPP catalytic hydrolysis; the metallomicelle made of oxamido-bridged dinuclear copper(II) complex and the surfactant showed high activity in the PNPP catalytic hydrolysis. |
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| Keywords: | PNPP hydrolysis dinuclear metallomicelle catalysis kinetics |
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