| Co[(C2H5O)2PS2]2(C12H8N2)的合成和晶体结构 |
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| 引用本文： | 李敏智,贺敏强,朱多林,俞运鹏.Co[(C2H5O)2PS2]2(C12H8N2)的合成和晶体结构[J].江苏大学学报(自然科学版),2005,26(3):274-276. |
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| 作者姓名： | 李敏智 贺敏强 朱多林 俞运鹏 |
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| 作者单位： | 江苏大学化学化工学院,江苏,镇江,212013 |
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| 基金项目： | 江苏省教育厅高校科学研究项目(02KJD150003) |
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| 摘 要： | 为研究二烃基二硫代磷酸酯合过渡金属配合物与氮碱加合物的性能，合成了二乙基二硫代磷酸酯合钴(Ⅲ)配合物，利用其与邻菲咯啉的加合反应，得到了Co(C2H5O)2PS2]2(C12H8N2)配合物并测定了它的晶体结构．Co(Ⅱ)与2个二硫代磷酸酯的4个硫原子和邻菲咯啉分子中的2个氮原子形成六配位的八面体结构，二硫代磷酸酯分子中的磷原子与2个硫原子2个氧原子形成四面体的结构．
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| 关 键 词： | 二乙基二硫代磷酸酯 钴配合物 邻菲咯啉 晶体结构 |
| 文章编号： | 1671-7775(2005)03-0274-03 |
| 修稿时间： | 2004年11月22 |
Synthesies and crystal structure of Co[(C2H5O)2 PS2]2 (C12 H8 N2) |
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| LI Min-zhi,HE Min-qiang,ZHU Duo-lin,YU Yun-Peng.Synthesies and crystal structure of Co[(C2H5O)2 PS2]2 (C12 H8 N2)[J].Journal of Jiangsu University:Natural Science Edition,2005,26(3):274-276. |
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| Authors: | LI Min-zhi HE Min-qiang ZHU Duo-lin YU Yun-Peng |
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| Abstract: | To study the properties of the adduct formation of dialkyldithiophosphate coordination compound of intergrade metal with nitrogen base, Co(C_2H_5O)_2PS_2] were synthesized. Co(C_2H_5O)_2PS_2]_2(C_~12 H_8N_2) were obtained by adductive reaction between Co(C_2H_5O)_2PS_2]_3 and phenanthroline. The crystal and molecule structures of title complex were analyzed. The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds. The central atom P is tetrahedrally surrounded by two sulphur atoms and two oxygen atoms in the diethyldithiophosphate ligand. |
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| Keywords: | diethyldithiophosphate cobalt complex phenanthroline crystal structure |
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