| 一种新型催化剂用于对硝基甲苯催化氢化的研究 |
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| 引用本文： | 马旭,李彩玲,田淑荣. 一种新型催化剂用于对硝基甲苯催化氢化的研究[J]. 哈尔滨商业大学学报(自然科学版), 2000, 16(2): 100-103 |
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| 作者姓名： | 马旭 李彩玲 田淑荣 |
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| 作者单位： | 哈尔滨宏华园食品公司,黑龙江哈尔滨,150001;黑龙江省路桥总公司第三工程处,黑龙江哈尔滨,150001;黑龙江大学化学化工学院,黑龙江哈尔滨,150080 |
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| 摘 要： | 制备了两种不同的含氮高分子-钯络合物,并研究了它们对对硝基甲苯的催化活性.结果发现,聚苯乙烯负载的苯乙烯-二乙烯基苯-马来酸酐交替共聚物与氨反应得到的高分子-钯络合物,在常温常压下对对硝基甲苯催化氢化有很高的活性,产物对甲苯胺的收率为100%.
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| 关 键 词： | 高分子-钯络合物 对硝基甲苯 对甲苯胺 |
| 修稿时间： | 1999-12-09 |
Studies on Catalytic Hydrogention of P-nitromethyl Benzene by a New Catalyst |
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| Ma Xu,Li Cai-ling,Tian Shu-rong. Studies on Catalytic Hydrogention of P-nitromethyl Benzene by a New Catalyst[J]. Journal of Harbin University of Commerce :Natural Sciences Edition, 2000, 16(2): 100-103 |
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| Authors: | Ma Xu Li Cai-ling Tian Shu-rong |
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| Abstract: | Two different kinds of palladium complexes of nitrogen containing polymere havebeen prepared and their catalytic actions for p -nitro -methyl benzfene have been invertigeted. Ithas been found that the kind of palladium complexes of the polymer obtained by the reaction of PS -supported styrene - divinylstyrene - malelic anhydride alternating copolymer withammonia is highly active hydrogenation catalyst of p -nitromethylbenzene at room temperatureand atmospheric pressure, and p-methyl aniline can be obtained in 100% yield. |
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| Keywords: | Pd-complex of polymer p-nitromethyl benzene P-methyl aniline |
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