| 吡啶－2，6－二甲酸铕（镧）配合物结构的NMR研究 |
| |
| 引用本文： | 杨秋青,何书美,李林书.吡啶－2，6－二甲酸铕（镧）配合物结构的NMR研究[J].河北师范大学学报(自然科学版),1995(4). |
| |
| 作者姓名： | 杨秋青 何书美 李林书 |
| |
| 作者单位： | 河北师范大学实验中心，河北师范学院化学系 |
| |
| 摘 要： | 合成了稀土肴（Ｅｕ）和镧（Ｌａ）与吡啶－２，６－二甲酸（Ｈ２ＤＰＣ）形成的二元配合物，并对上述配合物的结构作了核磁共振氢谱（１ＨＮＭＲ）、碳谱（１３ＣＮＭＲ）和氨谱（１４ＮＮＭＲ）及红外光谱（ＩＲ）的研究和比较．
|
| 关 键 词： | 稀土铕和镧，吡啶－2，6－二甲酸，~1H，~（13）C，~（14）NNMR，IR，配位数 |
NMR Study of the Complexes for Eu(La) with Pyridine-2, 6-dicarboxylic Acid |
| |
| Yang Qiuqing, He Shumei, Li Linshu.NMR Study of the Complexes for Eu(La) with Pyridine-2, 6-dicarboxylic Acid[J].Journal of Hebei Normal University,1995(4). |
| |
| Authors: | Yang Qiuqing He Shumei Li Linshu |
| |
| Abstract: | Solidified complexes of rare earth Eu3+ (La3+ )with pyridine-2, 6-dicarboxylic acid (H2DPC) were prepared. Their compositions were confirmed by elemental analysis as: Na3 En (DPC)3]. 2H2O3 Na3 La (DPC)3)]. 2H2O. Their structures were studied by 1 H,13C,14NNMR and IR spectra. The pyridine-2, 6-dicarboxylic acid is a tridentate ligand. The coordination number of europitlm and lanthanum are nine. |
| |
| Keywords: | rare earth Eu La pyridine-2 6-dicarboxylic acid 13HNMR 14 CNMR INNMR IR coordination ntlmber |
| 本文献已被 CNKI 等数据库收录！ |
