| 等浓度三级反应的无量纲参数法 |
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| 引用本文： | 皇起中. 等浓度三级反应的无量纲参数法[J]. 成都大学学报(自然科学版), 1994, 0(3) |
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| 作者姓名： | 皇起中 |
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| 作者单位： | 四川师范大学化学系 |
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| 摘 要： | 根据热动力学的基础理论，本文建立了等浓度三级反应的无量纲参数法．计算了２０℃时环氧氯丙烷与氢溴酸反应，１５和２０℃时甲醛与氮反应的速率常数．在误差范围内与文献值相符合．证明了等浓度三级反应的正确性，拓宽了无量纲参数法的应用范围
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| 关 键 词： | 热动力学，等浓度，无量纲参数，速率常数 |
The Method of Dimensionless Parameter for Third Order Reaction With Equal Concentration |
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| Huang Qizhong. The Method of Dimensionless Parameter for Third Order Reaction With Equal Concentration[J]. Journal of Chengdu University (Natural Science), 1994, 0(3) |
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| Authors: | Huang Qizhong |
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| Abstract: | On the basic theory of thermokinet,iCS proposed in pyevions articlethe methodof dimensionless parameter for third order reactions with equalconcentraction in this paper. The rate constant of the reactions f o repichlorohydrin with hydrobromicacid and formaldehydewith ammonia is calcataledat 15 and 20 (:. The rate constant of this reactioms calculated. is in agreementwith the vaules in literature.Thus the ratidity of this methodshould be proved,and the applied regin of this methodis extended. |
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| Keywords: | thermokinetics equal concentraction dimensionless parameter rate constant. |
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